fig16

Gradient engineering in functional complex oxide heterostructures

Figure 16. (A) PbZr1-xTixO3 phase diagram. (B) Bulk lattice parameter and calculated misfit strain. (C) Schematics of compositionally graded heterostructures. (A-C) Reproduced with permission[105]. Copyright 2015, American Chemical Society; (D) Characterization of compositionally graded PZT film (TOF-SIMS). (E) Zr/(Zr+Ti) molar ratio of PZT films and particles spontaneously synthesized in the same autoclaves measured using EDS. (F) SEM images of PZT films and particles by the hydrothermal synthesis. Schematic illustrations of the four steps in competitive growth are displayed below. (D-F) Reproduced with permission[107]. Copyright 2025, Springer Nature.

Microstructures
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