fig16

Figure 16. Plasmon-induced interfacial phenomena realizations (A) Hydrogen evolution profiles under visible and UV illumination using various metal-semiconductor systems^[273]. Copyright 2021, published by the Royal Society of Chemistry; (B) Schematic of a MOF-supported Au-based plasmonic system and corresponding H₂ generation performance^[274]. Copyright 2020, published by the American Chemical Society; (C) Photoelectrochemical cell based on p-n junction and corresponding J-V curves under simulated solar illumination^[276]. Copyright 2023, published by the Elsevier; (D) Chopped-light transient photocurrent responses of plasmonic-semiconductor composites^[275]. Copyright 2022, published by the Frontiers; (E) Structural modulation of ZnO-based photoelectrodes and their photocurrent responses^[277]. Copyright 2023, published by the Multidisciplinary Digital Publishing Institute; (F) Intensity ratio of bonding (top) vs. antibonding (gap) modes in plasmonic dimers as a function of interparticle gap size and linker molecules^[279]. Copyright 2024, published by the American Chemical Society; (G) Time-resolved charge density dynamics of HOMO and LUMO states under hot electron excitation in an Ag₁₉Pt-H₂O cluster^[280]. Copyright 2022, published by the Frontiers. UV: Ultraviolet; LED: light-emitting diode; TEOA: triethanolamine; MOF: metal organic framework; FTO:RHE: ZIF: zeolitic imidazolate framework; TNS: titanate nanosheet; NHE: normal hydrogen electrode; HOMO: highest occupied molecular orbital; LUMO: lowest unoccupied molecular orbital; MIL: Materials of Institute Lavoisier; J-V: current density-potential; BDP: bonding dipolar plasmon; TDP: transverse dipolar plasmon.