fig10

Figure 10. Dissolving ZIF-8 by ZIF-62. (A) Atomic configuration of a high-temperature liquid ZIF; (B) C_p and mass as a function of temperature for (ZIF-8)(ZIF-62) (20/80); (C) Structure factors S(q) of (ZIF-8)(ZIF-62) (20/80), a_g[(ZIF-8)_0.2(ZIF-62)_0.8] and ZIF-8, alongside that of a_gZIF-62; (D) Corresponding X-ray pair distribution functions D(r); (E) Temperature resolved SAXS profile of (ZIF-8)(ZIF-62) (20/80); (F) H₂ at 77 K gas isotherms for the zinc-based crystalline mixtures and glasses. (A-F) adapted with permission from reference^[98]. Copyright 2019, Royal Society of Chemistry. SAXS: Small-angle X-ray scattering; ZIF: zeolitic imidazolate framework.