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Reaction mechanisms, key challenges, and future prospects of zinc-ion/magnesium-based batteries: from fundamental researches to electrode/electrolyte engineering

Figure 8. (A) Nucleation Overpotential Comparison of Zn Deposition on COF@Cu and Bare Cu Electrodes. (B) After 50 cycles, surface SEM images of the bare Zn electrode and the COF-h-modified Zn anode. (C) Cycling performance of the COF@Zn||MnO2 and bare Zn||MnO2 batteries at 0.5 A g-1. (A-C) Reprinted with permission from[107]. Copyright 2022, American Chemical Society; (D) Schematic diagram of the DP additive’s action mechanism on bulk electrolyte and electrode/electrolyte interfaces. (E) Cycling performance of Zn||Zn symmetric cells. (F) CE of Zn||Cu asymmetric batteries. (G) Cycling performance at 4 A g-1. (D-G) Reprinted with permission from[108]. Copyright 2025, Royal Society of Chemistry. CEI: Cathode electrolyte interphase; COF: covalent organic framework; SEI: solid electrolyte interphase; SEM: scanning electron microscopy; DP: diethyl phosphoramidate.

Energy Materials
ISSN 2770-5900 (Online)
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