fig7

Structure-informed two-electron electrocatalysis for selective redox synthesis

Figure 7. (A) Charge density difference for O2 adsorbed on Fe3O4(220)-CNV. (B) HRTEM image of Fe3O4@TNC. (C) Free energy diagram at U = 0.7 V for the reduction of O2 to H2O2. (D) Capacitance current densities measured at 1.0 V using 40 mF cm-2 as the specific capacitance standard. (A-D) is reprinted with permission from Ref.[164]. Copyright © 2025 The Royal Society of Chemistry. (E) Optimized adsorption configuration of the *OCHO intermediate on the Zn-Sn (101) alloy surface. (F) TEM images of Zn/SnO2 at different magnifications; the inset is the corresponding SAED pattern. (G) Calculated reaction energy profiles for water oxidation on the Zn site of Zn/SnO2. (H) Faradaic efficiency of formate (FEHCOO-) over bare SnO2 and Zn/SnO2. (E-H) is reprinted with permission from Ref.[165]. Copyright © 2023 Wiley-VCH GmbH. (I) Adsorption model of O2 molecules on ZnO@ZnO2; red and gray spheres represent O and Zn atoms, respectively. (J) HRTEM image of ZnO treated with 0.4 mol L-1 H2O2. (K) LSV curves of ZnO, ZnO@ZnO2, and ZnO2 measured in 0.1 M K2SO4, with ring currents in the upper part and disk current densities in the lower part. (L) Calculated electron transfer number and H2O2 selectivity in 0.1 M K2SO4; the bottom panel shows electron transfer number and the upper panel shows H2O2 selectivity. (I-L) is reprinted with permission from Ref.[166]. Copyright © 2023 The Royal Society of Chemistry. (M) Image of the final obtained In2O3-x catalyst. (N) AC-TEM images of In2O3-x. (O) LSV curves of RRDE measurement at 5 mV s-1 and 1,600 rpm in O2-saturated 0.1 M KOH. (P) Calculated H2O2 selectivity of In2O3-x. (M-P) is reprinted with permission from Ref.[167]. Copyright © 2024 The Royal Society of Chemistry.

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