REFERENCES

1. Fang, R.; Zhao, S.; Sun, Z.; Wang, D. W.; Cheng, H. M.; Li, F. More reliable lithium-sulfur batteries: status, solutions and prospects. Adv. Mater. 2017, 29, 1606823.

2. Deng, R.; Wang, M.; Yu, H.; et al. Recent advances and applications toward emerging lithium-sulfur batteries: working principles and opportunities. Energy. Environ. Materials. 2022, 5, 777-99.

3. Wang, J.; He, Y. S.; Yang, J. Sulfur-based composite cathode materials for high-energy rechargeable lithium batteries. Adv. Mater. 2015, 27, 569-75.

4. Sun, C.; Sheng, J.; Zhang, Q.; et al. Self-extinguishing Janus separator with high safety for flexible lithium-sulfur batteries. Sci. China. Mater. 2022, 65, 2169-78.

5. Liu, B.; Fang, R.; Xie, D.; et al. Revisiting scientific issues for industrial applications of lithium-sulfur batteries. Energy. Environ. Mater. 2018, 1, 196-208.

6. Xue, W.; Shi, Z.; Suo, L.; et al. Intercalation-conversion hybrid cathodes enabling Li-S full-cell architectures with jointly superior gravimetric and volumetric energy densities. Nat. Energy. 2019, 4, 374-82.

7. Li, H.; Li, Y.; Zhang, L. Designing principles of advanced sulfur cathodes toward practical lithium‐sulfur batteries. SusMat 2022, 2, 34-64.

8. Li, J.; Li, X.; Fan, X.; et al. Holey graphene anchoring of the monodispersed nano-sulfur with covalently-grafted polyaniline for lithium sulfur batteries. Carbon 2022, 188, 155-65.

9. Li, S.; Fan, Z. Encapsulation methods of sulfur particles for lithium-sulfur batteries: a review. Energy. Storage. Mater. 2021, 34, 107-27.

10. Feng, L.; Yu, P.; Fu, X.; et al. Regulating polysulfide diffusion and deposition via rational design of core-shell active materials in Li-S batteries. ACS. Nano. 2022, 16, 7982-92.

11. Zhou, W.; Chen, M.; Zhao, D.; et al. Confined Co9S8 nanocrystals into N/S-Co-doped carbon nanofibers as a chainmail-like electrocatalyst for high-performance lithium-sulfur batteries with high sulfur loading. J. Colloid. Interface. Sci. 2022, 625, 187-96.

12. Xiao, Z.; Li, Z.; Li, P.; Meng, X.; Wang, R. Ultrafine Ti3C2 MXene nanodots-interspersed nanosheet for high-energy-density lithium-sulfur batteries. ACS. Nano. 2019, 13, 3608-17.

13. Chu, R.; Nguyen, T. T.; Bai, Y.; Kim, N. H.; Lee, J. H. Uniformly controlled treble boundary using enriched adsorption sites and accelerated catalyst cathode for robust lithium-sulfur batteries. Adv. Energy. Mater. 2022, 12, 2102805.

14. Yuan, S.; Xia, M.; Liu, Z.; et al. Dual synergistic effects between Co and Mo2C in Co/Mo2C heterostructure for electrocatalytic overall water splitting. Chem. Eng. J. 2022, 430, 132697.

15. Wang, J.; Yang, J.; Xie, J.; Xu, N. A Novel conductive polymer-sulfur composite cathode material for rechargeable lithium batteries. Adv. Mater. 2002, 14, 963-5.

16. Wei, S.; Ma, L.; Hendrickson, K. E.; Tu, Z.; Archer, L. A. Metal-sulfur battery cathodes based on PAN-sulfur composites. J. Am. Chem. Soc. 2015, 137, 12143-52.

17. Zhao, X.; Wang, C.; Li, Z.; Hu, X.; Abdul Razzaq, A.; Deng, Z. Sulfurized polyacrylonitrile for high-performance lithium sulfur batteries: advances and prospects. J. Mater. Chem. A. 2021, 9, 19282-97.

18. Xie, J.; Chen, J.; Guo, L.; et al. Deciphering the sulfur-involved bonding interactions in sulfurized polyacrylonitrile: the formation thermodynamics and the roles in electrochemical characteristics. ACS. Nano. 2025, 19, 3931-43.

19. Liu, J.; Wang, M.; Xu, N.; Qian, T.; Yan, C. Progress and perspective of organosulfur polymers as cathode materials for advanced lithium-sulfur batteries. Energy. Storage. Mater. 2018, 15, 53-64.

20. Chen, W. J.; Li, B. Q.; Zhao, C. X.; et al. Electrolyte regulation towards stable lithium-metal anodes in lithium-sulfur batteries with sulfurized polyacrylonitrile cathodes. Angew. Chem. Int. Ed. 2020, 59, 10732-45.

21. Doan, T. N. L.; Ghaznavi, M.; Zhao, Y.; et al. Binding mechanism of sulfur and dehydrogenated polyacrylonitrile in sulfur/polymer composite cathode. J. Power. Sources. 2013, 241, 61-9.

22. Zhang, Y.; Zhao, Y.; Yermukhambetova, A.; Bakenov, Z.; Chen, P. Ternary sulfur/polyacrylonitrile/Mg0.6Ni0.4O composite cathodes for high performance lithium/sulfur batteries. J. Mater. Chem. A. 2013, 1, 295-301.

23. Fang, L.; Xu, W.; Lyu, X.; et al. Suppressing the shuttle effects with FeCo/SPAN cathodes and high-concentration electrolytes for high-performance lithium-sulfur Batteries. ACS. Appl. Energy. Mater. 2023, 6, 795-801.

24. He, R.; Li, Y.; Wei, S.; et al. Construction of high-performance sulfurized poly(acrylonitrile) cathodes for lithium-sulfur batteries via catalytic and conductive regulation. J. Alloys. Compd. 2022, 919, 165838.

25. Wu, S.; Wang, W.; Shan, J.; et al. Conductive 1T-VS2-MXene heterostructured bidirectional electrocatalyst enabling compact Li-S batteries with high volumetric and areal capacity. Energy. Storage. Mater. 2022, 49, 153-63.

26. Wang, N.; Chen, B.; Qin, K.; et al. Octopus-inspired design of apical NiS2 nanoparticles supported on hierarchical carbon composites as an efficient host for lithium sulfur batteries with high sulfur loading. ACS. Appl. Mater. Interfaces. 2020, 12, 17528-37.

27. Li, Z.; Sami, I.; Yang, J.; Li, J.; Kumar, R. V.; Chhowalla, M. Lithiated metallic molybdenum disulfide nanosheets for high-performance lithium-sulfur batteries. Nat. Energy. 2023, 8, 84-93.

28. Li, D.; Li, Y.; Xu, C.; Zhao, S.; Zhang, Y.; Huo, P. Enhanced polysulfide adsorption and conversion on FeS2@CNF-modified separator for Li-S batteries. New. J. Chem. 2026, 50, 2891-5.

29. Li, Y.; He, R.; Liu, H.; et al. Construction of CoS2 reduction accelerator-modified sulfurized polyacrylonitrile nanofibers as high-performance cathode materials for practical lithium-sulfur batteries. ACS. Appl. Energy. Mater. 2023, 6, 8466-78.

30. Liu, Y.; Wang, W.; Wang, A.; Jin, Z.; Zhao, H.; Yang, Y. A polysulfide reduction accelerator - NiS2-modified sulfurized polyacrylonitrile as a high performance cathode material for lithium-sulfur batteries. J. Mater. Chem. A. 2017, 5, 22120-4.

31. Yang, W.; Zhao, H.; Chen, L.; et al. Ferrous sulfide-assisted hollow carbon spheres as sulfur host for advanced lithium-sulfur batteries. Chem. Eng. J. 2017, 326, 1040-7.

32. Lu, X.; Zhang, Q.; Wang, J.; et al. High performance bimetal sulfides for lithium-sulfur batteries. Chem. Eng. J. 2019, 358, 955-61.

33. Ren, X.; Wang, Q.; Pu, Y.; Sun, Q.; Sun, W.; Lu, L. Synergizing spatial confinement and dual-metal catalysis to boost sulfur kinetics in lithium-sulfur batteries. Adv. Mater. 2023, 35, e2304120.

34. Dong, H.; Ji, Y.; Wang, L.; et al. Bimetallic coupling strategy modulating electronic construction to accelerate sulfur redox reaction kinetics for high-energy flexible Li-S batteries. Small 2024, 20, e2406565.

35. Li, N.; Meng, T.; Ma, L.; et al. Curtailing carbon usage with addition of functionalized NiFe2O4 quantum dots: toward more practical S cathodes for Li-S cells. NanoMicro. Lett. 2020, 12, 145.

36. Wang, Z.; Song, C.; Shen, H.; Ma, S.; Li, G.; Li, Y. RuOx quantum dots loaded on graphdiyne for high-performance lithium-sulfur batteries. Adv. Mater. 2024, 36, e2307786.

37. Xu, Z. L.; Lin, S.; Onofrio, N.; et al. Exceptional catalytic effects of black phosphorus quantum dots in shuttling-free lithium sulfur batteries. Nat. Commun. 2018, 9, 4164.

38. Kresse, G.; Furthmüller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 1996, 6, 15-50.

39. Kresse, G.; Furthmüller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B. 1996, 54, 11169.

40. Kresse, G.; Joubert, D. From ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B. 1999, 59, 1758.

41. Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized gradient approximation made simple [Phys. Rev. Lett. 77, 3865 (1996)]. Phys. Rev. Lett. 1997, 78, 1396.

42. Babu, B.; Koutavarapu, R.; Shim, J.; Kim, J.; Yoo, K. Improved sunlight-driven photocatalytic abatement of tetracycline and photoelectrocatalytic water oxidation by tin oxide quantum dots anchored on nickel ferrite nanoplates. J. Electroanal. Chem. 2021, 900, 115699.

43. Miah, M.; Hota, P.; Mondal, T. K.; Chen, R.; Saha, S. K. Mixed metal sulfides (FeNiS2) nanosheets decorated reduced graphene oxide for efficient electrode materials for supercapacitors. J. Alloys. Compd. 2023, 933, 167648.

44. Liu, H.; Zhang, Y.; Li, Y.; Han, N.; Liu, H.; Zhang, X. Solid-state transformations of active materials in the pores of sulfurized-polyacrylonitrile fiber membranes via nucleophilic reactions for high-loading and free-standing lithium-sulfur battery cathodes. Adv. Fiber. Mater. 2024, 6, 772-85.

45. Hwang, T. H.; Jung, D. S.; Kim, J. S.; Kim, B. G.; Choi, J. W. One-dimensional carbon-sulfur composite fibers for Na-S rechargeable batteries operating at room temperature. Nano. Lett. 2013, 13, 4532-8.

46. Wang, X.; Qian, Y.; Wang, L.; et al. Sulfurized polyacrylonitrile cathodes with high compatibility in both ether and carbonate electrolytes for ultrastable lithium-sulfur batteries. Adv. Funct. Mater. 2019, 29, 1902929.

47. Chen, X.; Peng, L.; Wang, L.; et al. Ether-compatible sulfurized polyacrylonitrile cathode with excellent performance enabled by fast kinetics via selenium doping. Nat. Commun. 2019, 10, 1021.

48. Lu, J.; Zhang, Y.; Huang, J.; et al. Melamine foam-derived N-doped carbon framework and graphene-supported sulfurized polyacrylonitrile for high performance lithiumsulfur battery cathode. J. Energy. Storage. 2025, 118, 116330.

49. Abdul Razzaq, A.; Chen, G.; Zhao, X.; et al. Cobalt coordination with pyridines in sulfurized polyacrylonitrile cathodes to form conductive pathways and catalytic M-N4S sites for accelerated Li-S kinetics. J. Energy. Chem. 2021, 61, 170-8.

50. Lu, J.; Zhang, Y.; Huang, J.; et al. A free-standing sulfide polyacrylonitrile/reduced graphene oxide film cathode with nacre-like architecture for high-performance lithium-sulfur batteries. J. Power. Sources. 2025, 629, 235916.

51. Shao, J.; Huang, C.; Zhu, Q.; et al. Flexible CNT-interpenetrating hierarchically porous sulfurized polyacrylonitrile (CIHP-SPAN) electrodes for high-rate lithium-sulfur (Li-S) batteries. Nanomaterials. 2024, 14, 1155.

52. Hao, C.; Liu, J.; Wang, Q.; et al. High volumetric capacity FeS2/SPAN composite with promoted kinetics for Li-S battery. ACS. Nano. 2025, 19, 25385-94.

53. Wang, K.; Guan, Y.; Jin, Z.; Wang, W.; Wang, A. Te0.045S0.955PAN composite with high average discharge voltage for Li-S battery. J. Energy. Chem. 2019, 39, 249-55.

54. Haridas, A. K.; Heo, J.; Li, X.; et al. A flexible and free-standing FeS/sulfurized polyacrylonitrile hybrid anode material for high-rate sodium-ion storage. Chem. Eng. J. 2020, 385, 123453.

55. Liu, H.; Xu, Q.; Zhang, Y.; Han, N.; Liu, H.; Zhang, X. Multifunctional heterostructure CoS2/FeS2 catalysts for enhancing high-performance lithium-sulfurized polyacrylonitrile batteries through intrinsic electric fields. Chin. Chem. Lett. 2025, 111084.

56. Wang, J.; Du, Z.; Lv, G.; et al. Enhancing the backbone regularity of sulfurized polyacrylonitrile for long-life Li-SPAN batteries. J. Mater. Chem. A. 2025, 13, 21545-54.

57. Gao, G.; Zheng, F.; Pan, F.; Wang, L. W. Theoretical investigation of 2D conductive microporous coordination polymers as Li-S battery cathode with ultrahigh energy density. Adv. Energy. Mater. 2018, 8, 1801823.

58. Zhao, B.; Ren, Z.; Tan, G.; Li, Z.; Xie, J. Defects on Li2S@graphene cathode improves the performance of lithium-sulfur battery, A theoretical study. Acta. Mater. 2022, 226, 117632.

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