Special Topic
   Topic: Recent Advances in Negative Thermal Expansion and Related Materials
Guest Editor
Special Topic Introduction
The vast majority of materials expand as the temperature increases, giving problems in many technological and engineering applications, such as fracture due to thermal stress or changes in properties of devices arising from their dimensional changes. For this reason, the development of materials with zero thermal expansion or, even better, with controlled thermal expansion, represents a challenge for materials design.
After the discovery in 1996 of a large negative thermal expansion (NTE) over a wide temperature range in zirconium tungstate, the interest in NTE has rapidly grown and the goal of controlling thermal expansion has become possible. NTE phenomenon is known to arise from a range of different mechanisms, such as low-energy vibrational modes in open-framework materials, magnetic and ferroelectric transitions, or charge transfer in the case of intermetallic compounds. To date, many NTE materials have been discovered and different methods are under investigation to achieve the control of thermal expansion, but there is still a long way to go.
This Special Issue aims to collect research papers and review articles of the 4th International Symposium on Negative Thermal Expansion and Related Materials (ISNTE-4), scheduled on July 5-7, 2023, in Padua, Italy, but is also open to external contributions. The Special Issue will focus on the recent advances in negative thermal expansion and related materials and will include (not limited to) the following subjects:
● NTE phenomena of phonon, electronic and magnetic origin;
● NTE materials (oxides, fluorides, metal organic frameworks, intermetallics, organic molecular materials, polymers, meta materials, etc.);
● different strategies for controlling the thermal expansion of materials and related applications;
● relationship between thermal expansion and thermo-responsive properties.
 After the discovery in 1996 of a large negative thermal expansion (NTE) over a wide temperature range in zirconium tungstate, the interest in NTE has rapidly grown and the goal of controlling thermal expansion has become possible. NTE phenomenon is known to arise from a range of different mechanisms, such as low-energy vibrational modes in open-framework materials, magnetic and ferroelectric transitions, or charge transfer in the case of intermetallic compounds. To date, many NTE materials have been discovered and different methods are under investigation to achieve the control of thermal expansion, but there is still a long way to go.
This Special Issue aims to collect research papers and review articles of the 4th International Symposium on Negative Thermal Expansion and Related Materials (ISNTE-4), scheduled on July 5-7, 2023, in Padua, Italy, but is also open to external contributions. The Special Issue will focus on the recent advances in negative thermal expansion and related materials and will include (not limited to) the following subjects:
● NTE phenomena of phonon, electronic and magnetic origin;
● NTE materials (oxides, fluorides, metal organic frameworks, intermetallics, organic molecular materials, polymers, meta materials, etc.);
● different strategies for controlling the thermal expansion of materials and related applications;
● relationship between thermal expansion and thermo-responsive properties.
Keywords
Negative thermal expansion, controlling thermal expansion, zero thermal expansion, NTE materials, thermos-responsive materials
 Submission Deadline
29 Feb 2024
 Submission Information
For Author Instructions, please refer to https://www.oaepublish.com/microstructures/author_instructions
 For Online Submission, please login at https://www.oaecenter.com/login?JournalId=microstructures&IssueId=microstructures2402291449
Submission Deadline: 29 Feb 2024
 Contacts: Yanlin Huang, Assistant Editor, [email protected]
Published Articles
Longitudinal zero thermal expansion in Re-Fe (R = Tb, Er)  eutectic alloys with high fracture resistance
 Open Access  Research Article  9 Aug 2024
  
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 On the thermal expansion of the tetragonal phase of MAPbI3 and MAPbBr3
 Open Access  Review  8 Aug 2024
  
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 Transition from isotropic positive to negative thermal expansion by local Zr6O8 node distortion in MOF-801
 Open Access  Research Article  21 Apr 2024
  
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 Zentropy theory for accurate prediction of free energy, volume, and thermal expansion without fitting parameters
 Open Access  Review  22 Jan 2024
  
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 First-principles study on the negative/zero area compressibility in Ag3BO3 with “wine-rack” architecture
 Open Access  Research Article  1 Jan 2024
  
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