REFERENCES

1. Ma, E.; Ding, J. Tailoring structural inhomogeneities in metallic glasses to enable tensile ductility at room temperature. Mater. Today. 2016, 19, 568-79.

2. Greer, A. L. Metallic glasses. Science 1995, 267, 1947-53.

3. Liu, Z.; Yang, Y.; Liu, C. Yielding and shear banding of metallic glasses. Acta. Mater. 2013, 61, 5928-36.

4. Yazdani, A.; Dewitt, D.; Huang, W.; et al. Mechanical properties of an ultrahard in situ amorphous steel matrix composite. Adv. Eng. Mater. 2024, 26, 2400257.

5. Di, S.; Wang, Q.; Zhou, J.; et al. Enhancement of plasticity for FeCoBSiNb bulk metallic glass with superhigh strength through cryogenic thermal cycling. Scr. Mater. 2020, 187, 13-8.

6. Qiao, J.; Wang, Y.; Pelletier, J.; Keer, L. M.; Fine, M. E.; Yao, Y. Characteristics of stress relaxation kinetics of La₆₀Ni₁₅Al₂₅ bulk metallic glass. Acta. Mater. 2015, 98, 43-50.

7. Xu, N.; Huang, Y.; Cao, Y.; Li, S.; Wang, Y. D. Novel casting CoCrNiAl eutectic high entropy alloys with high strength and good ductility. Microstructures 2023, 3, 2023015.

8. Argon, A. Plastic deformation in metallic glasses. Acta. Metall. 1979, 27, 47-58.

9. Wang, Q.; Lou, H.; Xu, D.; et al. Shear straining promoted structural transition in bulk metallic glasses. Scr. Mater. 2024, 249, 116168.

10. Greer, A.; Cheng, Y.; Ma, E. Shear bands in metallic glasses. Mater. Sci. Eng. R. Rep. 2013, 74, 71-132.

11. Ketov, S. V.; Sun, Y. H.; Nachum, S.; et al. Rejuvenation of metallic glasses by non-affine thermal strain. Nature 2015, 524, 200-3.

12. Wu, G.; Liu, S.; Wang, Q.; et al. Substantially enhanced homogeneous plastic flow in hierarchically nanodomained amorphous alloys. Nat. Commun. 2023, 14, 3670.

13. Wright, W.; Saha, R.; Nix, W. Deformation mechanisms of the Zr₄₀Ti₁₄Ni₁₀Cu₁₂Be₂₄ bulk metallic glass. Mater. Trans. 2001, 42, 642-9.

14. Wang, W. H. The elastic properties, elastic models and elastic perspectives of metallic glasses. Prog. Mater. Sci. 2012, 57, 487-656.

15. Turnbull, D. Under what conditions can a glass be formed? Contemp. Phys. 1969, 10, 473-88.

16. Huang, R.; Suo, Z.; Prevost, J.; Nix, W. Inhomogeneous deformation in metallic glasses. J. Mech. Phys. Solids. 2002, 50, 1011-27.

17. Falk, M. L.; Langer, J. S. Dynamics of viscoplastic deformation in amorphous solids. Phys. Rev. E. 1998, 57, 7192-205.

18. Schuh, C.; Hufnagel, T.; Ramamurty, U. Mechanical behavior of amorphous alloys. Acta. Mater. 2007, 55, 4067-109.

19. Sun, W.; Li, T.; Wang, Y.; et al. Thermally-driven structural inhomogeneity and serrated plastic flow in TaTiZr amorphous medium-entropy alloy. Acta. Mater. 2025, 286, 120764.

20. Wang, W. H. Dynamic relaxations and relaxation-property relationships in metallic glasses. Prog. Mater. Sci. 2019, 106, 100561.

21. Tao, K.; Qiao, J.; He, Q.; Song, K.; Yang, Y. Revealing the structural heterogeneity of metallic glass: mechanical spectroscopy and nanoindentation experiments. Int. J. Mech. Sci. 2021, 201, 106469.

22. Wang, Z.; Sun, B. A.; Bai, H. Y.; Wang, W. H. Evolution of hidden localized flow during glass-to-liquid transition in metallic glass. Nat. Commun. 2014, 5, 5823.

23. Ma, E. Controlling plastic instability. Nat. Mater. 2003, 2, 7-8.

24. Lv, J.; Yin, D.; Wang, F.; Yang, Y.; Ma, M.; Zhang, X. Influence of sub-Tg annealing on microstructure and crystallization behavior of TiZr-based bulk metallic glass. J. Non. Cryst. Solids. 2021, 565, 120855.

25. Song, K.; Pauly, S.; Sun, B.; et al. Formation of Cu-Zr-Al-Er bulk metallic glass composites with enhanced deformability. Intermetallics 2012, 30, 132-8.

26. He, L.; Wu, S.; Dong, A.; et al. Selective laser melting of dense and crack-free AlCoCrFeNi_2.1 eutectic high entropy alloy: synergizing strength and ductility. J. Mater. Sci. Technol. 2022, 117, 133-45.

27. Hadibeik, S.; Ghasemi-Tabasi, H.; Burn, A.; Lani, S.; Spieckermann, F.; Eckert, J. Controlling the glassy state toward structural and mechanical enhancement: additive manufacturing of bulk metallic glass using advanced laser beam shaping technology. Adv. Funct. Mater. 2023, 34, 2311118.

28. Argon, A.; Kuo, H. Plastic flow in a disordered bubble raft (an analog of a metallic glass). Mater. Sci. Eng. 1979, 39, 101-9.

29. Long, Z.; Tao, P.; Wang, G.; et al. Effect of Nb and Ta addition on mechanical properties of Zr-based bulk metallic glasses and composites. J. Alloys. Compd. 2022, 912, 165071.

30. Kong, L.; Tao, P.; Xiong, Z.; Yan, X.; Yang, Y. Effect of deep cryogenic cycle treatment on the microstructure and mechanical properties of Zr₄₆Cu₄₆Al₄Ti₄ bulk metallic glass. Intermetallics 2024, 175, 108504.

31. Wang, W. H. Correlation between relaxations and plastic deformation, and elastic model of flow in metallic glasses and glass-forming liquids. J. Appl. Phys. 2011, 110, 053521.

32. Yu, H. B.; Shen, X.; Wang, Z.; Gu, L.; Wang, W. H.; Bai, H. Y. Tensile plasticity in metallic glasses with pronounced β relaxations. Phys. Rev. Lett. 2012, 108, 015504.

33. Greer, A. L.; Sun, Y. H. Stored energy in metallic glasses due to strains within the elastic limit. Philos. Mag. 2016, 96, 1643-63.

34. Li, X.; Wang, J.; Ke, H.; Yang, C.; Wang, W. Extreme rejuvenation and superior stability in a metallic glass. Mater. Today. Phys. 2022, 27, 100782.

35. Yuan, X.; Şopu, D.; Spieckermann, F.; et al. Maximizing the degree of rejuvenation in metallic glasses. Scr. Mater. 2022, 212, 114575.

36. Lee, M.; Lee, K.; Das, J.; Thomas, J.; Kühn, U.; Eckert, J. Improved plasticity of bulk metallic glasses upon cold rolling. Scr. Mater. 2010, 62, 678-81.

37. Scudino, S.; Jerliu, B.; Surreddi, K.; Kühn, U.; Eckert, J. Effect of cold rolling on compressive and tensile mechanical properties of Zr_52.5Ti₅Cu₁₈Ni_14.5Al₁₀ bulk metallic glass. J. Alloys. Compd. 2011, 509, S128-30.

38. Stolpe, M.; Kruzic, J.; Busch, R. Evolution of shear bands, free volume and hardness during cold rolling of a Zr-based bulk metallic glass. Acta. Mater. 2014, 64, 231-40.

39. Pan, J.; Ivanov, Y. P.; Zhou, W. H.; Li, Y.; Greer, A. L. Strain-hardening and suppression of shear-banding in rejuvenated bulk metallic glass. Nature 2020, 578, 559-62.

40. Dmowski, W.; Yokoyama, Y.; Chuang, A.; et al. Structural rejuvenation in a bulk metallic glass induced by severe plastic deformation. Acta. Mater. 2010, 58, 429-38.

41. Gunderov, D.; Churakova, A.; Boltynjuk, E.; et al. Observation of shear bands in the Vitreloy metallic glass subjected to HPT processing. J. Alloys. Compd. 2019, 800, 58-63.

42. Nieh, T.; Yang, Y.; Lu, J.; Liu, C. Effect of surface modifications on shear banding and plasticity in metallic glasses: an overview. Prog. Nat. Sci. Mater. Int. 2012, 22, 355-63.

43. Chen, W.; Chan, K.; Chen, S.; Guo, S.; Li, W.; Wang, G. Plasticity enhancement of a Zr-based bulk metallic glass by an electroplated Cu/Ni bilayered coating. Mater. Sci. Eng. A. 2012, 552, 199-203.

44. Qu, R.; Wu, S.; Wang, S.; Wang, X.; Zhang, Z. Shear banding stability and fracture of metallic glass: effect of external confinement. J. Mechan. Phys. Solids. 2020, 138, 103922.

45. Ding, J.; Patinet, S.; Falk, M. L.; Cheng, Y.; Ma, E. Soft spots and their structural signature in a metallic glass. Proc. Natl. Acad. Sci. USA. 2014, 111, 14052-6.

46. Hubek, R.; Seleznev, M.; Binkowski, I.; Peterlechner, M.; Divinski, S. V.; Wilde, G. The impact of micro-alloying on relaxation dynamics in Pd40Ni40P20 bulk metallic glass. J. Appl. Phys. 2018, 124, 225103.

47. Zhou, H.; Hubek, R.; Peterlechner, M.; Wilde, G. Two-stage rejuvenation and the correlation between rejuvenation behavior and the boson heat capacity peak of a bulk metallic glass. Acta. Mater. 2019, 179, 308-16.

48. Ebner, C.; Escher, B.; Gammer, C.; Eckert, J.; Pauly, S.; Rentenberger, C. Structural and mechanical characterization of heterogeneities in a CuZr-based bulk metallic glass processed by high pressure torsion. Acta. Mater. 2018, 160, 147-57.

49. Qiu, X.; Thompson, J. W.; Billinge, S. J. L. PDFgetX2: a GUI-driven program to obtain the pair distribution function from X-ray powder diffraction data. J. Appl. Crystallogr. 2004, 37, 678.

50. Lan, S.; Blodgett, M.; Kelton, K. F.; Ma, J. L.; Fan, J.; Wang, X. Structural crossover in a supercooled metallic liquid and the link to a liquid-to-liquid phase transition. Appl. Phys. Lett. 2016, 108, 211907.

51. Ding, J.; Ma, E.; Asta, M.; Ritchie, R. O. Second-nearest-neighbor correlations from connection of atomic packing motifs in metallic glasses and liquids. Sci. Rep. 2015, 5, 17429.

52. Révész, Á.; Arjmandabasi, T.; Schafler, E.; Browne, D. J.; Kovács, Z. Comprehensive thermal analysis of a high stability Cu-Zr-Al bulk metallic glass subjected to high-pressure torsion. J. Therm. Anal. Calorim. 2023, 148, 2323-34.

53. Louzguine-Luzgin, D.; Ketov, S.; Wang, Z.; Miyama, M.; Tsarkov, A.; Churyumov, A. Plastic deformation studies of Zr-based bulk metallic glassy samples with a low aspect ratio. Mater. Sci. Eng. A. 2014, 616, 288-96.

54. Ren, Z. Q.; Churakova, A.; Wang, X.; et al. Enhanced tensile strength and ductility of bulk metallic glasses Zr_52.5Cu_17.9Al₁₀Ni_14.6Ti₅ via high-pressure torsion. Mater. Sci. Eng. A. 2021, 803, 140485.

55. Ma, D.; Stoica, A. D.; Wang, X. Power-law scaling and fractal nature of medium-range order in metallic glasses. Nat. Mater. 2008, 8, 30-4.

56. Li, F.; Wang, T.; He, Q.; et al. Micromechanical mechanism of yielding in dual nano-phase metallic glass. Scr. Mater. 2018, 154, 186-91.

57. Yao, Z.; Zhu, H.; Lou, Y.; et al. Composition engineering of short-range-ordered polyhedra in Ni-Mo-P-B metallic glass for electrochemical sensing. Mater. Today. 2026, 94, 103245.

58. Knuyt, G.; De Schepper, L.; Stals, L. M. Calculation of some metallic glass properties, based on the use of a Gaussian distribution for the nearest-neighbour distance. Philos. Mag. B. 2006, 61, 965-88.