fig10

Figure 10. (A) Structures and properties of typical carbonate and ether solvents, along with the bonding structures and properties of siloxane solvents; Figure 10A is reprinted with permission from Ref.^[264]. Copyright © 2025 Wiley; (B) AIMD simulation of the DDS decomposition process of siloxanes on the lithium (110) surface; Figure 10B is reprinted with permission from Ref.^[265]. Copyright © 2025 Wiley; (C) Design strategy of a Si-containing solvent; Figure 10C is reprinted with permission from Ref.^[266]. Copyright © 2025 American Chemical Society; (D) Schematic illustration of MODOL molecule design; Figure 10D is reprinted with permission from Ref.^[267]. Copyright © 2025 Wiley; (E) Dual-anchoring design strategy for the synergistic effect of two anchoring agents; (F) Comparison of ¹⁷O- NMR spectra between G2 and G2/TTE; Figure 10E and F is reprinted with permission from Ref.^[269]. Copyright © 2025 Wiley; (G) Design strategy for electrolytes; (H) Schematic illustration of the “push-pull” mechanism; Figure 10G and H is reprinted with permission from Ref.^[272]. Copyright © 2024 American Chemical Society. DME: Dimethyl ether; DMM: dimethoxymethane; DMMS: dimethyldimethoxysilane; TMMS: trimethylsilane; DOL: 1,3-dioxolane; MODOL: 2-methoxy-1,3-dioxolane; TTE: 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether; THF: tetrahydrofuran; ESP: electrostatic potential; DEE: 1,2-diethoxyethane; DMC: dimethyl carbonate; EC: 1,2-diethoxyethane; DMS: dimethyl sulfite; DTD: 1,3,2-Dioxathiolane-2,2-dioxide; DTF: 2,2-difluoroethyl triflate; OTE: 1,1,2,2-Tetrafluoroethyl-2,2,2-trifluoroethyl ether; DDS: 2,2-dimethoxypropane; AIMD: Ab initio molecular dynamics; NMR: nuclear magnetic resonance spectroscopy.