REFERENCES
1. Yang, H.; Wu, H. H.; Ge, M.; et al. Simultaneously dual modification of Ni-rich layered oxide cathode for high-energy lithium-ion batteries. Adv. Funct. Mater. 2019, 29, 1808825.
2. Zhou, Y.; Ding, Y.; Chen, Y.; et al. Thermal degradation of lithium-ion battery cathodes: a machine learning prediction of stability and safety. Energy. Mater. 2025, 5, 500077.
3. Kim, D.; Jayasubramaniyan, S.; Kim, S.; et al. Multi-layered yolk-shell design containing carbon bridge connection for alloying anodes in lithium-ion batteries. Energy. Mater. 2025, 5, 500072.
4. Pham, H. Q.; Kim, G.; Jung, H. M.; Song, S. W. Fluorinated polyimide as a novel high-voltage binder for high-capacity cathode of lithium-ion batteries. Adv. Funct. Mater. 2017, 28, 1704690.
5. Lu, X.; Zhang, X.; Tan, C.; et al. Multi-length scale microstructural design of lithium-ion battery electrodes for improved discharge rate performance. Energy. Environ. Sci. 2021, 14, 5929-46.
6. Feng, X.; Gao, Y.; Ben, L.; Yang, Z.; Wang, Z.; Chen, L. Enhanced electrochemical performance of Ti-doped Li1.2Mn0.54Co0.13Ni0.13O2 for lithium-ion batteries. J. Power. Sources. 2016, 317, 74-80.
7. Xie, X.; Cui, J.; Liu, Z.; et al. Constructing a surface spinel layer to stabilize the oxygen frame of Li-rich layered oxides. Inorg. Chem. Front. 2022, 9, 5828-39.
8. Kuo, J.; Li, C. Water-based process to the preparation of nickel-rich Li(Ni0.8Co0.1Mn0.1)O2 Cathode. J. Electrochem. Soc. 2020, 167, 100504.
9. Elizalde-segovia, R.; Das, P.; Zayat, B.; Irshad, A.; Thompson, B. C.; Narayanan, S. R. Understanding the role of π-conjugated polymers as binders in enabling designs for high-energy/high-rate lithium metal batteries. J. Electrochem. Soc. 2021, 168, 110541.
10. Nitou, M. V. M.; Fang, X.; Wang, J.; et al. The integration of LiNi0.8Co0.1Mn0.1O2 coatings on separators for elevated battery performance. Energy. Mater. 2025, 5, 500018.
11. Kimura, K.; Sakamoto, T.; Mukai, T.; et al. Improvement of the cyclability and coulombic efficiency of Li-ion batteries using Li[Ni0.8Co0.15Al0.05]O2 cathode containing an aqueous binder with pressurized CO2 gas treatment. J. Electrochem. Soc. 2018, 165, A16-20.
12. Loghavi, M. M.; Bahadorikhalili, S.; Lari, N.; Moghim, M. H.; Babaiee, M.; Eqra, R. The effect of crystalline microstructure of PVDF binder on mechanical and electrochemical performance of lithium-ion batteries cathode. Zeitschrift. für. Physikalische. Chemie. 2020, 234, 381-97.
13. Tsai, P.; Wen, B.; Wolfman, M.; et al. Single-particle measurements of electrochemical kinetics in NMC and NCA cathodes for Li-ion batteries. Energy. Environ. Sci. 2018, 11, 860-71.
14. Dong, T.; Mu, P.; Zhang, S.; Zhang, H.; Liu, W.; Cui, G. How do polymer binders assist transition metal oxide cathodes to address the challenge of high-voltage lithium battery applications? Electrochem. Energ. Rev. 2021, 4, 545-65.
15. Zhao, T.; Meng, Y.; Ji, R.; Wu, F.; Li, L.; Chen, R. Maintaining structure and voltage stability of Li-rich cathode materials by green water-soluble binders containing Na+ ions. J. Alloys. Compd. 2019, 811, 152060.
16. Cui, X.; Wang, X.; Pan, Q. Achieving fast and stable Li+ transport in lithium-sulfur battery via a high ionic conduction and high adhesion solid polymer electrolyte. Energy. Mater. 2023, 3, 300034.
17. Zhou, X.; Yang, J.; Wang, R.; Zhang, W.; Yun, S.; Wang, B. Advances in lithium-ion battery materials for ceramic fuel cells. Energy. Mater. 2022, 2, 200041.
18. Brandt, T. G.; Temeche, E.; Tuokkola, A. R.; et al. Nanocomposite Li- and Mn-rich spinel cathodes characterized with a green, aqueous binder system. Chem. Eng. J. 2024, 479, 147419.
19. Gan, Q.; Qin, N.; Guo, H.; et al. Consolidating the vulnerable interphase of Ni-rich layered cathode by multifunctional water-based binder. ACS. Energy. Lett. 2024, 9, 1562-71.
20. Jeong, Y. H.; Won, G.; Kim, S.; et al. A tough, adhesive, and protective binder shield for stabilizing high‐nickel cathodes in lithium‐ion batteries. Adv. Energy. Mater. 2025, 15, e02765.
21. Mazouzi, D.; Karkar, Z.; Reale Hernandez, C.; et al. Critical roles of binders and formulation at multiscales of silicon-based composite electrodes. J. Power. Sources. 2015, 280, 533-49.
22. Zhong, X.; Han, J.; Chen, L.; et al. Binding mechanisms of PVDF in lithium ion batteries. Appl. Surf. Sci. 2021, 553, 149564.
23. Pasquier, A. D.; Disma, F.; Bowmer, T.; Gozdz, A. S.; Amatucci, G.; Tarascon, J. M. Differential scanning calorimetry study of the reactivity of carbon anodes in plastic Li-ion batteries. J. Electrochem. Soc. 2019, 145, 472-7.
24. Zhang, Z.; Ma, J.; Xiao, M.; et al. Poly (propylene carbonate) with extremely alternating structure used as binders for high-loading cathodes by solvent-free method in high-performance NCM811 batteries. Materials. (Basel). 2024, 17, 5466.
25. Kim, H.; Kang, D. H.; Lee, J.; et al. Solvophobic binder crystallinity-tailored advances in solvent-free thick cathodes for high-energy lithium metal batteries. Adv. Funct. Mater. 2025, 2420104.
26. Park, J.; Lee, S.; Choi, W. Surface-intensive doping of Na via pH-dependent polymer for Co-free Ni-rich cathodes in Li-ion batteries. Chem. Eng. J. 2024, 488, 150807.
27. Albers, S.; Timmermann, J.; Brake, T.; et al. Enabling aqueous processing of Ni-rich layered oxide cathodes via systematic modification of biopolymer (polysaccharide)-based binders. Adv. Energy. and. Sustain. Res. 2024, 5, 2400117.
28. Wang, Y.; Fang, Y.; Huang, L.; et al. Stabilizing Nickel-rich cathodes in aqueous process through nanocellulose as water barrier. Adv. Funct. Mater. 2024, 35, 2413865.
29. Xu, Y.; Wang, Y.; Dong, N.; et al. Novel polyimide binder for achieving high-rate capability and long-term cycling stability of LiNi0.8Co0.1Mn0.1O2 cathode via constructing polar and micro-branched crosslinking network structure. J. Energy. Chem. 2023, 76, 19-31.
30. Yu, M.; Wang, Y.; Wang, Z.; et al. Weakened capacity fading of Li-rich cathode via aqueous binder for advanced lithium ion batteries. J. Electrochem. Soc. 2019, 166, A4122-7.
31. Watanabe, T.; Hirai, K.; Ando, F.; et al. Surface double coating of a LiNiaCobAl1-a-bO2 (a > 0.85) cathode with TiOx and Li2CO3 to apply a water-based hybrid polymer binder to Li-ion batteries. RSC. Adv. 2020, 10, 13642-54.
32. Jeong, D.; Kwon, D. S.; Kim, H. J.; Shim, J. Striking a balance: exploring optimal functionalities and composition of highly adhesive and dispersing binders for high-nickel cathodes in lithium-ion batteries. Adv. Energy. Mater. 2023, 13, 2302845.
33. Chen, B.; Zhang, Z.; Wu, C.; et al. Aliphatic polycarbonate-based binders for high-loading cathodes by solvent-free method used in high performance LiFePO4|Li batteries. Materials. (Basel). 2024, 17, 3153.
34. Ko, H.; Kim, M.; Hong, S. Y.; et al. Plasma-assisted mechanochemistry to covalently bond ion-conducting polymers to Ni-rich cathode materials for improved cyclic stability and rate capability. ACS. Appl. Energy. Mater. 2022, 5, 4808-16.
35. Wu, Q.; Ha, S.; Prakash, J.; Dees, D. W.; Lu, W. Investigations on high energy lithium-ion batteries with aqueous binder. Electrochim. Acta. 2013, 114, 1-6.
36. Jang, J.; Ahn, J.; Ahn, J.; et al. A fluorine-free binder with organic-inorganic crosslinked networks enabling structural stability of Ni‐rich layered cathodes in lithium-ion batteries. Adv. Funct. Mater. 2024, 34, 2410866.
37. Watanabe, T.; Yokokawa, T.; Yamada, M.; et al. Surface coating of a LiNixCoyAl1-x-yO2 (x > 0.85) cathode with Li3PO4 for applying a water-based hybrid polymer binder during Li-ion battery preparation. RSC. Adv. 2021, 11, 37150-61.
38. Das, P.; Elizalde-Segovia, R.; Zayat, B.; et al. Enhancing the ionic conductivity of poly(3,4-propylenedioxythiophenes) with oligoether side chains for use as conductive cathode binders in lithium-ion batteries. Chem. Mater. 2022, 34, 2672-86.
39. Lv, M.; Zhao, R.; Hu, Z.; et al. Binder design strategies for cathode materials in advanced secondary batteries. Energy. Environ. Sci. 2024, 17, 4871-906.
40. Nam, M. G.; Moon, J.; Kim, M.; et al. p-phenylenediamine-bridged binder-electrolyte-unified supramolecules for versatile lithium secondary batteries. Adv. Mater. 2024, 36, e2304803.
41. Wu, F.; Li, W.; Chen, L.; et al. Polyacrylonitrile-polyvinylidene fluoride as high-performance composite binder for layered Li-rich oxides. J. Power. Sources. 2017, 359, 226-33.
42. Hawley, W. B.; Parejiya, A.; Bai, Y.; Meyer, H. M.; Wood, D. L.; Li, J. Lithium and transition metal dissolution due to aqueous processing in lithium-ion battery cathode active materials. J. Power. Sources. 2020, 466, 228315.
43. Hawley, W. B.; Meyer, H. M.; Li, J. Enabling aqueous processing for LiNi0.80Co0.15Al0.05O2 (NCA)-based lithium-ion battery cathodes using polyacrylic acid. Electrochim. Acta. 2021, 380, 138203.
44. Laszczynski, N.; Von zamory, J.; Kalhoff, J.; Loeffler, N.; Chakravadhanula, V. S. K.; Passerini, S. Improved performance of VOx‐coated Li‐rich NMC electrodes. ChemElectroChem 2015, 2, 1768-73.
45. Yang, J.; Li, P.; Zhong, F.; et al. Suppressing voltage fading of Li‐rich oxide cathode via building a well-protected and partially-protonated surface by polyacrylic acid binder for cycle-stable Li‐ion batteries. Adv. Energy. Mater. 2020, 10, 1904264.
46. Notake, K.; Gunji, T.; Kokubun, H.; et al. The application of a water-based hybrid polymer binder to a high-voltage and high-capacity Li-rich solid-solution cathode and its performance in Li-ion batteries. J. Appl. Electrochem. 2016, 46, 267-78.
47. Zhang, G.; Qiu, B.; Xia, Y.; et al. Double-helix-superstructure aqueous binder to boost excellent electrochemical performance in Li-rich layered oxide cathode. J. Power. Sources. 2019, 420, 29-37.
48. Zhou, C. C.; Su, Z.; Gao, X. L.; Cao, R.; Yang, S. C.; Liu, X. H. Ultra‐high‐energy lithium‐ion batteries enabled by aligned structured thick electrode design. Rare. Metals. 2021, 41, 14-20.
49. Pham, H. Q.; Lee, J.; Jung, H. M.; Song, S. Non-flammable LiNi0.8Co0.1Mn0.1O2 cathode via functional binder; stabilizing high-voltage interface and performance for safer and high-energy lithium rechargeable batteries. Electrochim. Acta. 2019, 317, 711-21.
50. Huang, X.; You, H.; Yan, X.; et al. Environmentally sustainable lithium-ion battery cathode binders based on cellulose nanocrystals. J. Mater. Chem. A. 2024, 12, 33015-22.
51. Yin, Z.; Zhang, T.; Zhang, S.; et al. Understanding the role of water-soluble guar gum binder in reducing capacity fading and voltage decay of Li-rich cathode for Li-ion batteries. Electrochim. Acta. 2020, 351, 136401.
52. Hwa, Y.; Frischmann, P. D.; Helms, B. A.; Cairns, E. J. Aqueous-processable redox-active supramolecular polymer binders for advanced lithium/sulfur cells. Chem. Mater. 2018, 30, 685-91.
53. Qiu, J.; Wu, S.; Yang, Y.; et al. Aqueous supramolecular binder for a lithium-sulfur battery with flame-retardant property. ACS. Appl. Mater. Interfaces. 2021, 13, 55092-101.
54. Hu, L.; Zhang, X.; Zhao, P.; et al. Gradient H-bonding binder enables stable high-areal-capacity Si-based anodes in pouch cells. Adv. Mater. 2021, 33, e2104416.
55. Li, Z.; Wu, G.; Yang, Y.; et al. An ion‐conductive grafted polymeric binder with practical loading for silicon anode with high interfacial stability in lithium-ion batteries. Adv. Energy. Mater. 2022, 12, 2201197.
56. Liu, H.; Chen, T.; Xu, Z.; Liu, Z.; Yang, J.; Chen, J. High-safety and long-life silicon-based lithium-ion batteries via a multifunctional binder. ACS. Appl. Mater. Interfaces. 2020, 12, 54842-50.
57. Chang, B.; Kim, J.; Cho, Y.; et al. Highly elastic binder for improved cyclability of nickel-rich layered cathode materials in lithium-ion batteries. Adv. Energy. Mater. 2020, 10, 2001069.
58. Wang, Y.; Dong, N.; Liu, B.; et al. Enhanced electrochemical performance of the LiNi0.8Co0.1Mn0.1O2 cathode via in-situ nanoscale surface modification with poly(imide-siloxane) binder. Chem. Eng. J. 2022, 450, 137959.
59. Liu, T.; Chu, Q.; Yan, C.; Zhang, S.; Lin, Z.; Lu, J. Interweaving 3D network binder for high-areal-capacity Si anode through combined hard and soft polymers. Adv. Energy. Mater. 2018, 9, 1802645.
60. Qi, K.; Wang, Y.; Dong, N.; et al. Novel polyimide binders integrated with soft and hard functional segments ensuring long-term high-voltage operating stability of high-energy NCM811 lithium-ion batteries up to 4.5 V. Appl. Energy. 2022, 320, 119282.
61. Yang, J.; Shi, M.; Wu, W.; et al. Cross-linked siloxane-based copolymer binder with combined hardness and softness for stable silicon anodes in Li-ion batteries. J. Mater. Sci. 2021, 56, 20126-37.
62. Jiao, X.; Yin, J.; Xu, X.; et al. Highly energy-dissipative, fast self-healing binder for stable Si anode in lithium-ion batteries. Adv. Funct. Mater. 2020, 31, 2005699.
63. Li, J.; Zhang, B.; Yuan, X.; et al. Benzene ring structural design strategy toward well-balanced thermal and electrical properties in epoxy dielectric polymers. Compos. Part. B:. Eng. 2025, 297, 112308.
64. Li, T.; Chai, S.; Liu, B.; Zhao, C.; Li, H. All‐carbon backbone aromatic polymers for proton exchange membranes. J. Polym. Sci. 2023, 61, 2796-814.
65. Mu, P.; Zhang, H.; Jiang, H.; et al. Bioinspired antiaging binder additive addressing the challenge of chemical degradation of electrolyte at cathode/electrolyte interphase. J. Am. Chem. Soc. 2021, 143, 18041-51.
66. Liu, Z.; Dong, T.; Mu, P.; Zhang, H.; Liu, W.; Cui, G. Interfacial chemistry of vinylphenol-grafted PVDF binder ensuring compatible cathode interphase for lithium batteries. Chem. Eng. J. 2022, 446, 136798.
67. Naga, N.; Inose, D.; Ishida, T.; Kubota, K.; Nageh, H.; Nakano, T. Synthesis of polymer networks by means of addition reactions of tri-amine and poly(ethylene glycol) diacrylate or diglycidyl ether compounds. Polym. Bull. 2020, 78, 2745-63.
68. Talakesh, M. M.; Sadeghi, M.; Chenar, M. P.; Khosravi, A. Gas separation properties of poly(ethylene glycol)/poly(tetramethylene glycol) based polyurethane membranes. J. Membr. Sci. 2012, 415-416, 469-77.
69. Chang, Z.; Zhang, M.; Hudson, A. G.; et al. Synthesis and properties of segmented polyurethanes with triptycene units in the hard segment. Polymer 2013, 54, 6910-7.
70. Bocharova, V.; Sokolov, A. P. Perspectives for polymer electrolytes: a view from fundamentals of ionic conductivity. Macromolecules 2020, 53, 4141-57.
71. Costa, C. M.; Merazzo, K. J.; Gonçalves, R.; Amos, C.; Lanceros-Méndez, S. Magnetically active lithium-ion batteries towards battery performance improvement. iScience 2021, 24, 102691.
72. Zhang, S.; Gu, H.; Pan, H.; et al. A novel strategy to suppress capacity and voltage fading of Li‐ and Mn‐rich layered oxide cathode material for lithium-ion batteries. Adv. Energy. Mater. 2016, 7, 1601066.
73. Kim, Y. M.; Murugesan, K.; Chang, Y. Y.; Kim, E. J.; Chang, Y. S. Degradation of polybrominated diphenyl ethers by a sequential treatment with nanoscale zero valent iron and aerobic biodegradation. J. Chem. Technol. Biotechnol. 2011, 87, 216-24.
74. Arias, K. S.; Climent, M. J.; Corma, A.; Iborra, S. Biomass-derived chemicals: synthesis of biodegradable surfactant ether molecules from hydroxymethylfurfural. ChemSusChem 2014, 7, 210-20.
75. Tang, S.; Baker, G. A.; Zhao, H. Ether- and alcohol-functionalized task-specific ionic liquids: attractive properties and applications. Chem. Soc. Rev. 2012, 41, 4030-66.
76. Pedaballi, S.; Li, C. Aqueous processed Ni-rich Li(Ni0.8Co0.1Mn0.1)O2 cathodes along with water-based binders and a carbon fabric as 3-D conductive host. J. Electrochem. Soc. 2021, 168, 120538.
77. Wang, L.; Ma, Y.; Li, Q.; et al. 1,3,6-Hexanetricarbonitrile as electrolyte additive for enhancing electrochemical performance of high voltage Li-rich layered oxide cathode. J. Power. Sources. 2017, 361, 227-36.
78. Lee, S. H.; Hwang, J. Y.; Park, S. J.; Park, G. T.; Sun, Y. K. Adiponitrile (C6H8N2): a new Bi-functional additive for high-performance Li‐metal batteries. Adv. Funct. Mater. 2019, 29, 1902496.
79. Li, S.; Zhao, D.; Wang, P.; Cui, X.; Tang, F. Electrochemical effect and mechanism of adiponitrile additive for high-voltage electrolyte. Electrochim. Acta. 2016, 222, 668-77.
80. Jin, M.; Li, B.; Hu, L.; Zhao, P.; Zhang, Q.; Song, J. Functional copolymer binder for nickel-rich cathode with exceptional cycling stability at high temperature through coordination interaction. J. Energy. Chem. 2021, 60, 156-61.
81. Xi, Y.; Liu, Y.; Zhang, D.; Jin, S.; Zhang, R.; Jin, M. Comparative study of the electrochemical performance of LiNi0.5Co0.2Mn0.3O2 and LiNi0.8Co0.1Mn0.1O2 cathode materials for lithium ion batteries. Solid. State. Ionics. 2018, 327, 27-31.
82. Li, W.; Wu, K.; Feng, H.; et al. Atomic layer deposition of ultrafine Pd nanoparticles for enhancing the rate capability of LiNi0.8Co0.1Mn0.1O2 cathode. Tungsten 2022, 4, 346-55.
83. Gan, Z.; Hu, G.; Peng, Z.; Cao, Y.; Tong, H.; Du, K. Surface modification of LiNi0.8Co0.1Mn0.1O2 by WO3 as a cathode material for LIB. Appl. Surf. Sci. 2019, 481, 1228-38.
84. Chen, S.; He, T.; Su, Y.; et al. Ni-rich LiNi0.8CO0.1Mn0.1O2 oxide coated by dual-conductive layers as high performance cathode material for lithium-ion batteries. ACS. Appl. Mater. Interfaces. 2017, 9, 29732-43.
85. Wang, Y.; Dong, N.; Liu, B.; Tian, G.; Qi, S.; Wu, D. Self-adaptive gel poly(imide-siloxane) binder ensuring stable cathode-electrolyte interface for achieving high-performance NCM811 cathode in lithium-ion batteries. Energy. Storage. Mater. 2023, 56, 621-30.
86. Xu, Y.; Chafi, F. Z.; Chen, P.; et al. More than just a binder: versatile block copolymer enhances the electrochemical performance of a nickel-rich cathode. ACS. Appl. Polym. Mater. 2023, 5, 4654-63.
87. Li, R. Bai, C.-J.; Liu, H.; et al. New insights into the mechanism of enhanced performance of Li[Ni0.8Co0.1Mn0.1]O2 with a polyacrylic acid-modified binder. ACS. Appl. Mater. Interfaces. 2021, 13, 10064-70.
88. Wandt, J.; Freiberg, A. T.; Ogrodnik, A.; Gasteiger, H. A. Singlet oxygen evolution from layered transition metal oxide cathode materials and its implications for lithium-ion batteries. Mater. Today. 2018, 21, 825-33.
89. Freiberg, A. T. S.; Roos, M. K.; Wandt, J.; de Vivie-Riedle, R.; Gasteiger, H. A. Singlet oxygen reactivity with carbonate solvents used for Li-ion battery electrolytes. J. Phys. Chem. A. 2018, 122, 8828-39.
90. Hatsukade, T.; Schiele, A.; Hartmann, P.; Brezesinski, T.; Janek, J. Origin of carbon dioxide evolved during cycling of nickel-rich layered NCM cathodes. ACS. Appl. Mater. Interfaces. 2018, 10, 38892-9.
91. Rinkel, B. L. D.; Hall, D. S.; Temprano, I.; Grey, C. P. Electrolyte oxidation pathways in lithium-ion batteries. J. Am. Chem. Soc. 2020, 142, 15058-74.
92. Kim, N. Y.; Moon, J.; Ryou, M. H.; et al. Amphiphilic bottlebrush polymeric binders for high-mass-loading cathodes in lithium-ion batteries. Adv. Energy. Mater. 2021, 12, 2102109.
93. Xiao, P.; Shi, T.; Huang, W.; Ceder, G. Understanding surface densified phases in Ni-rich layered compounds. ACS. Energy. Lett. 2019, 4, 811-8.
94. Kleiner, K.; Dixon, D.; Jakes, P.; et al. Fatigue of LiNi0.8Co0.15Al0.05O2 in commercial Li ion batteries. J. Power. Sources. 2015, 273, 70-82.
95. Zhuang, G. V.; Chen, G.; Shim, J.; Song, X.; Ross, P. N.; Richardson, T. J. Li2CO3 in LiNi0.8Co0.15Al0.05O2 cathodes and its effects on capacity and power. J. Power. Sources. 2004, 134, 293-7.
96. Kim, J.; Lee, H.; Cha, H.; Yoon, M.; Park, M.; Cho, J. Prospect and reality of Ni‐rich cathode for commercialization. Adv. Energy. Mater. 2017, 8, 1702028.
97. Vadivel, S.; Sawangphruk, M. Prelithiated perfluoro-ionomer as an alternative binder for the state-of-the-art Ni-rich LiNi0.8Co0.15Al0.05O2 cathode of next-generation lithium-ion batteries. J. Mater. Chem. A. 2020, 8, 20714-24.
98. Das, P.; Zayat, B.; Wei, Q.; et al. Dihexyl-Substituted Poly(3,4-Propylenedioxythiophene) as a dual ionic and electronic conductive cathode binder for lithium-ion batteries. Chem. Mater. 2020, 32, 9176-89.
99. Tanabe, T.; Liu, Y.; Miyamoto, K.; et al. Synthesis of water-resistant thin TiOx layer-coated high-voltage and high-capacity LiNiaCobAl1-a-bO2 (a > 0.85) cathode and its cathode performance to apply a water-based hybrid polymer binder to Li-Ion batteries. Electrochim. Acta. 2017, 258, 1348-55.
100. Nayak, P. K.; Erickson, E. M.; Schipper, F.; et al. Review on challenges and recent advances in the electrochemical performance of high capacity Li‐ and Mn‐rich cathode materials for Li‐Ion batteries. Adv. Energy. Mater. 2017, 8, 1702397.
101. Yang, J.; Xia, Y. Suppressing the phase transition of the layered Ni-rich oxide cathode during high-voltage cycling by introducing low-content Li2MnO3. ACS. Appl. Mater. Interfaces. 2016, 8, 1297-308.
102. Pedaballi, S.; Li, C. Effects of surface modification and organic binder type on cell performance of water-processed Ni-rich Li(Ni0.8Co0.1Mn0.1)O2 cathodes. J. Power. Sources. 2020, 472, 228552.
103. Yan, W.; Xie, Y.; Jiang, J.; et al. Enhanced rate performance of Al-doped Li-rich layered cathode material via nucleation and post-solvothermal method. ACS. Sustainable. Chem. Eng. 2018, 6, 4625-32.
104. Pan, H.; Zhang, S.; Chen, J.; et al. Li- and Mn-rich layered oxide cathode materials for lithium-ion batteries: a review from fundamentals to research progress and applications. Mol. Syst. Des. Eng. 2018, 3, 748-803.
105. Zhang, S. J.; Deng, Y. P.; Wu, Q. H.; et al. Sodium-alginate-based binders for lithium-rich cathode materials in lithium-ion batteries to suppress voltage and capacity fading. ChemElectroChem 2018, 5, 1321-9.
106. Pham, H. Q.; Hwang, E.; Kwon, Y.; Song, S. Understanding the interfacial phenomena of a 4.7 V and 55 °C Li-ion battery with Li-rich layered oxide cathode and graphite anode and its correlation to high-energy cycling performance. J. Power. Sources. 2016, 323, 220-30.
107. Iturrondobeitia, A.; Kvasha, A.; Lopez Del Amo, J.; et al. A comparative study of aqueous and organic processed Li1.2Ni0.2Mn0.6O2 Li-rich cathode materials for advanced lithium-ion batteries. Electrochim. Acta. 2017, 247, 420-5.
108. Chen, H.; Ling, M.; Hencz, L.; et al. Exploring chemical, mechanical, and electrical functionalities of binders for advanced energy-storage devices. Chem. Rev. 2018, 118, 8936-82.
109. Liu, J.; Galpaya, D. G. D.; Yan, L.; et al. Exploiting a robust biopolymer network binder for an ultrahigh-areal-capacity Li-S battery. Energy. Environ. Sci. 2017, 10, 750-5.
110. Liu, J.; Zhang, Q.; Zhang, T.; Li, J. T.; Huang, L.; Sun, S. G. A robust ion-conductive biopolymer as a binder for Si anodes of lithium-ion batteries. Adv. Funct. Mater. 2015, 25, 3599-605.
111. Kong, D.; Hu, J.; Chen, Z.; et al. Ti-gradient doping to stabilize layered surface structure for high performance high‐Ni oxide cathode of Li‐ion battery. Adv. Energy. Mater. 2019, 9, 1901756.
112. Zhang, Q.; Liu, K.; Li, C.; et al. The surface triple-coupling on single crystalline cathode for lithium ion batteries. Nano. Energy. 2021, 86, 106096.
113. Qiu, L.; Xiang, W.; Tian, W.; et al. Polyanion and cation co-doping stabilized Ni-rich Ni-Co-Al material as cathode with enhanced electrochemical performance for Li-ion battery. Nano. Energy. 2019, 63, 103818.
114. Liu, X.; Wang, D.; Liu, G.; et al. Distinct charge dynamics in battery electrodes revealed by in situ and operando soft X-ray spectroscopy. Nat. Commun. 2013, 4, 2568.
115. Ulvestad, A.; Singer, A.; Cho, H. M.; et al. Single particle nanomechanics in operando batteries via lensless strain mapping. Nano. Lett. 2014, 14, 5123-7.
116. Xu, J.; Sun, M.; Qiao, R.; et al. Elucidating anionic oxygen activity in lithium-rich layered oxides. Nat. Commun. 2018, 9, 947.
117. Song, J.; Li, B.; Chen, Y.; et al. A high-performance Li-Mn-O Li-rich cathode material with rhombohedral symmetry via intralayer Li/Mn disordering. Adv. Mater. 2020, 32, e2000190.
118. Liu, S.; Liu, Z.; Shen, X.; et al. Surface doping to enhance structural integrity and performance of Li‐rich layered oxide. Adv. Energy. Mater. 2018, 8, 1802105.
119. Cui, C.; Ji, X.; Wang, P.; et al. Integrating multiredox centers into one framework for high-performance organic Li-ion battery cathodes. ACS. Energy. Lett. 2019, 5, 224-31.
120. Yang, J.; Xiong, P.; Shi, Y.; et al. Rational molecular design of benzoquinone-derived cathode materials for high-performance lithium-ion batteries. Adv. Funct. Mater. 2020, 30, 1909597.


