REFERENCES

1. Turner, J. M. The matter of a clean energy future. Science 2022, 376, 1361-1361.

2. Lukatskaya, M. R.; Dunn, B.; Gogotsi, Y. Multidimensional materials and device architectures for future hybrid energy storage. Nat. Commun. 2016, 7, 12647.

3. Yang, Z.; Zhang, J.; Kintner-Meyer, M. C.; et al. Electrochemical energy storage for green grid. Chem. Rev. 2011, 111, 3577-613.

4. Xu, K. Electrolytes and interphases in Li-ion batteries and beyond. Chem. Rev. 2014, 114, 11503-618.

5. Quilty, C. D.; Wu, D.; Li, W.; et al. Electron and ion transport in lithium and lithium-ion battery negative and positive composite electrodes. Chem. Rev. , 2023, 1327-63.

6. Wang, H.; Yang, X.; Wu, Q.; et al. Encapsulating silica/antimony into porous electrospun carbon nanofibers with robust structure stability for high-efficiency lithium storage. ACS. Nano. 2018, 12, 3406-16.

7. Goodenough, J. B.; Kim, Y. Challenges for rechargeable Li batteries. Chem. Mater. 2010, 22, 587-603.

8. Ruan, J.; Hu, J.; Li, Q.; et al. Current collector interphase design for high-energy and stable anode-less sodium batteries. Nat. Sustain. 2025, 8, 530-41.

9. Chai, W.; Qiao, Y.; Wang, Z.; et al. HKUST-1 derived CuSx@C nanocomposites with TiO₂ coating and rich sulfur vacancies for excellent high-rate long-life sodium-ion batteries. J. Power. Sources. 2026, 665, 239009.

10. Liu, P.; Miao, L.; Sun, Z.; Chen, X.; Jiao, L. Sodiophilic substrate induces NaF-rich solid electrolyte interface for dendrite-free sodium metal anode. Adv. Mater. 2024, 36, e2406058.

11. Yu, Y.; Xu, S.; Yang, Y.; et al. Highly sodiophilic heterostructures toward dendrite-free sodium metal batteries. Adv. Funct. Mater. 2024, 34, 2401914.

12. Rui, X.; Zhang, X.; Xu, S.; et al. A low-temperature sodium-ion full battery: superb kinetics and cycling stability. Adv. Funct. Mater. 2021, 31, 2009458.

13. Huang, F.; Xu, P.; Fang, G.; Liang, S. In-depth understanding of interfacial Na⁺ Behaviors in sodium metal anode: migration, desolvation, and deposition. Adv. Mater. 2024, 36, e2405310.

14. Gao, W.; Lu, Y.; Tan, X.; et al. Sodiophilic design for sodium-metal batteries: progress and prospects. Energy. Environ. Sci. 2025, 18, 1630-57.

15. Shi, D.; Lv, X.; Yang, Y.; et al. NaBi_x/NaV_yO_z hybrid interfacial layer enables stable and dendrite-free sodium anodes. Small 2024, 20, e2402206.

16. Damircheli, R.; Hoang, B.; Ferrari, V. C.; Lin, C. Highly uniform nitride-rich artificial solid electrolyte interphase enabled by nano-silicon nitride for superior performance in advanced sodium metal batteries. J. Mater. Chem. A. 2024, 12, 31949-58.

17. Moorthy, M.; Thangavel, R.; An, S. Y.; Anilkumar, A.; Han, D.; Lee, Y. S. Recent trends in artificial SEI layers for controlling dendrite formation and enhancing cycle life: toward stable and durable sodium metal batteries. Small 2025, 21, e2502974.

18. Yin, H.; Cao, Y.; Wang, Y.; et al. Artificial solid electrolyte interphase for sodium metal batteries: mechanistic insights and design strategies. Energy. Environ. Mater. 2025, 8, e70077.

19. Sun, H.; Zhu, G.; Xu, X.; et al. A safe and non-flammable sodium metal battery based on an ionic liquid electrolyte. Nat. Commun. 2019, 10, 3302.

20. Wu, Y.; Zhu, J.; Ni, J.; Li, L. Liquid metal-modified 3D Cu foam for dendrite-free sodium plating. Small 2024, 20, e2405357.

21. Chen, R.; Lu, X.; He, Q.; et al. Sb₂S₃ nanorod hierarchies enabling homogeneous sodium deposition for dendrite-free sodium-metal batteries. ACS. Appl. Energy. Mater. 2022, 5, 10952-60.

22. Hu, C.; Qi, J.; Zhang, Y.; et al. Room-temperature all-solid-state sodium battery based on bulk interfacial superionic conductor. Nano. Lett. 2021, 21, 10354-60.

23. Chen, C.; Yao, W.; Tang, Y. Emerging solutions to enable the efficient use of sodium metal anodes: progress and perspectives. Adv. Funct. Mater. 2024, 34, 2310833.

24. Chen, Q.; He, H.; Hou, Z.; et al. Building an artificial solid electrolyte interphase with high-uniformity and fast ion diffusion for ultralong-life sodium metal anodes. J. Mater. Chem. A. 2020, 8, 16232-7.

25. Lu, X.; Chen, R.; Shen, S.; et al. Spatially confined in situ formed sodiophilic-conductive network for high-performance sodium metal batteries. Nano. Lett. 2024, 24, 5490-7.

26. Xu, P.; Huang, F.; Liu, Z.; Guo, S.; Liang, S.; Fang, G. In situ construction of NaF-rich solid electrolyte interphase with metallic Ce sites for stable anode-free sodium metal batteries. Angew. Chem. Int. Ed. 2025, 64, e202515566.

27. Li, Z.; Qin, H.; Tian, W.; et al. 3D Sb-based composite framework with gradient sodiophilicity for ultrastable sodium metal anodes. Adv. Funct. Mater. 2024, 34, 2301554.

28. Li, Z.; Miao, L.; Lin, G.; et al. Na (100)-textured electrode embedded with Sb-doped SnO₂ nanoparticles for dendrite-free sodium metal batteries. Adv. Energy. Mater. 2024, 14, 2402284.

29. Yang, G.; Li, N.; Sun, C. High-performance sodium metal batteries with sodium-bismuth alloy anode. ACS. Appl. Energy. Mater. 2020, 3, 12607-12.

30. Su, D.; Dou, S.; Wang, G. Bismuth: a new anode for the Na-ion battery. Nano. Energy. 2015, 12, 88-95.

31. Zhou, S.; Sun, Z.; Zhang, J.; et al. Single-atom engineering for synergistic nucleation and interfacial regulation enabling durable anode-free sodium metal batteries. Adv. Mater. 2026, 38, e13154.

32. Kyono, A.; Kimata, M. Structural variations induced by difference of the inert pair effect in the stibnite-bismuthinite solid solution series (Sb,Bi)₂S₃. Am. Mineral. 2004, 89, 932-40.

33. Li, Y.; Huang, L.; Li, B.; et al. Co-nucleus 1D/2D heterostructures with Bi₂S₃ nanowire and MoS₂ monolayer: one-step growth and defect-induced formation mechanism. ACS. Nano. 2016, 10, 8938-46.

34. Yu, H.; Zhao, Y.; Zhang, J.; et al. Coordination regulation strategy in fabricating Bi₂S₃@CNFs composites with uniform dispersion for robust sodium storage. Inorg. Chem. 2024, 63, 21441-9.

35. Yuan, M.; Wang, H.; Xu, T.; et al. Unlocking the ultrafast deposition kinetics within Bi-tailored core-shell structured carbon nanofibers for highly efficient and ultrastable sodium metal batteries. Angew. Chem. Int. Ed. 2025, 64, e202417930.

36. Zhu, X.; Wang, Y.; Wang, W.; et al. Stable sodium metal anodes enabled by an in-situ generated mixed-ion/electron-conducting interface. Chem. Eng. J. 2022, 446, 136917.

37. Ma, M.; Lu, Y.; Yan, Z.; Chen, J. In situ synthesis of a bismuth layer on a sodium metal anode for fast interfacial transport in sodium-oxygen batteries. Batteries. Supercaps. 2019, 2, 663-7.

38. Moorthy, M.; Thangavel, R.; Ganesan, B. K.; et al. Ultra-high areal capacity, ultra-long life, dendrite-free sodium metal anode enabled by antimony-based Na-ion conducting artificial SEI layers. Chem. Eng. J. 2024, 498, 155234.

39. Dai, J.; Wang, H.; Zhang, R.; et al. Co-sputtering strategy to construct robust sodiophilic interfaces for anode-less sodium metal batteries. Chem. Commun. 2024, 60, 11120-3.

40. Arab, J.; Mishra, D. K.; Kannojia, H. K.; Adhale, P.; Dixit, P. Fabrication of multiple through-holes in non-conductive materials by electrochemical discharge machining for RF MEMS packaging. J. Mater. Process. Technol. 2019, 271, 542-53.

41. Sun, B.; Li, P.; Zhang, J.; et al. Dendrite-free sodium-metal anodes for high-energy sodium-metal batteries. Adv. Mater. 2018, 30, 1801334.

42. He, G.; Xiao, Y.; Zhang, T.; et al. Localized solvent-anchored carboxylate ester electrolyte enables wide temperature and fast charging sodium metal batteries. Adv. Mater. 2026, 38, e23324.

43. Zhang, W.; Lu, Q.; Sun, G.; et al. Sodiophilic interface induces a NaF-rich solid electrolyte interface for stable sodium-metal batteries under harsh conditions. Nano. Lett. 2025, 25, 6092-100.