REFERENCES
1. Wang, J.; Zhang, J.; Cheng, X.; et al. Electrode/electrolyte interface studies of rechargeable Li batteries with interface-specific sum frequency generation spectroscopy. J. Am. Chem. Soc. 2025, 147, 44633-51.
2. Wang, J.; Tang, B.; Wu, J.; et al. Revitalizing dendritic lithium with atomic modulator-decorated suspension electrolyte for durable lithium metal batteries. Sci. Adv. 2026, 12, eaef9111.
3. Zhang, J.; Liu, F.; He, R.; et al. Taming interfacial ion-dipole interactions with d-orbital delocalized electron catalysis expediates low-temperature Li metal batteries. Adv. Mater. 2026, 38, e10894.
4. Zhang, Z.; Han, W. From liquid to solid-state lithium metal batteries: fundamental issues and recent developments. NanoMicro. Lett. 2024, 16, 24.
5. Jiang, Z.; Chen, S.; Wei, C.; et al. Enabling superior electrochemical performance of NCA cathode in Li5.5PS4.5Cl1.5-based solid-state batteries with a dual-electrolyte layer. Chin. Chem. Lett. 2024, 35, 108561.
6. Nguyen, M. H.; Niu, C.; Ngo, N. M.; Chen, J.; Park, S. Recent progress on metal-organic framework-based separators for quasi-solid-state lithium metal batteries. Energy. Mater. 2025, 5, 500093.
7. Hou, Y.; Chen, Z.; Zhang, R.; Cui, H.; Yang, Q.; Zhi, C. Recent advances and interfacial challenges in solid-state electrolytes for rechargeable Li-air batteries. Exploration 2023, 3, 20220051.
8. Chen, G.; Liu, X.; Liu, Z.; et al. Novel “sandwich” configuration with ALD-coating layers on electrode/electrolyte interfaces for durable all-solid-state lithium metal batteries with high-voltage cathodes. Energy. Mater. 2025, 5, 500064.
9. Park, G.; Jeon, D. W.; Jang, I.; et al. Investigation of the effects of heteroatom doping on von-Alpen-type NASICON electrolytes and its applications to solid-state sodium batteries. J. Adv. Ceram. 2025, 14, 9221138.
10. Zhang, A.; Bi, Z.; Yang, E.; et al. Formulating electrophilic electrolyte for in situ stabilization of 4.8 V Li-Rich batteries with 100% initial coulombic efficiency. Angew. Chem. Int. Ed. 2025, 64, e202502603.
11. Zhou, X.; Chang, C. Y.; Yu, D.; et al. Li2ZrF6 protective layer enabled high-voltage LiCoO2 positive electrode in sulfide all-solid-state batteries. Nat. Commun. 2025, 16, 112.
12. Zhang, Y.; Liu, H.; Liu, F.; et al. Dual-anion-rich polymer electrolytes for high-voltage solid-state lithium metal batteries. ACS. Nano. 2025, 19, 3197-209.
13. Yu, T.; Liu, Y.; Li, H.; Sun, Y.; Guo, S.; Zhou, H. Ductile inorganic solid electrolytes for all-solid-state lithium batteries. Chem. Rev. 2025, 125, 3595-662.
14. Jiang, Z.; Peng, H.; Liu, Y.; et al. A Versatile Li6.5In0.25P0.75S5I sulfide electrolyte triggered by ultimate-energy mechanical alloying for all-solid-state lithium metal batteries. Adv. Energy. Mater. 2021, 11, 2101521.
15. Shin, S.; Kang, S. H.; Kim, G.; et al. Intergranular amorphous film in GeO2-enriched Li1.5Al0.5Ti1.5(PO4)3 composite electrolytes for high-performance solid-state lithium-ion batteries. Composites. Part. B. 2024, 280, 111478.
16. He, C.; Ying, H.; Cai, L.; et al. Tailoring stable PEO-based electrolyte/electrodes interfaces via molecular coordination regulating enables 4.5 V solid-state lithium metal batteries. Adv. Funct. Mater. 2024, 34, 2410350.
17. Xu, H.; Liu, S.; Li, Z.; et al. Synergistic effect of Ti3C2Tx MXene/PAN nanofiber and LLZTO particles on high-performance PEO-based solid electrolyte for lithium metal battery. J. Colloid. Interface. Sci. 2024, 668, 634-45.
18. Zhang, X.; Cheng, S.; Fu, C.; et al. Advancements and challenges in organic-inorganic composite solid electrolytes for all-solid-state lithium batteries. NanoMicro. Lett. 2024, 17, 2.
19. Chen, P.; Ding, B.; Dou, H.; Zhang, X. Ceramic-polymer composite solid-state electrolytes for solid-state lithium metal batteries: mechanism, strategy, and prospect. Small 2025, 21, e2503743.
20. Deng, Y.; Zhu, T.; Cheng, Y.; et al. Recent advances in functional cellulose-based materials: classification, properties, and applications. Adv. Fiber. Mater. 2024, 6, 1343-68.
21. Kim, H.; Lee, C.; Jo, J.; et al. Multilayered separators with core-shell structured nanocellulose-SiO2 nanocomposites for lithium-ion batteries. Carbohydr. Polym. 2025, 362, 123677.
22. Wang, R.; Dong, W.; Song, Z.; et al. Ion-conducting molecular-grafted sustainable cellulose quasi-solid composite electrolyte for high stability solid-state lithium-metal batteries. Adv. Funct. Mater. 2024, 34, 2402461.
23. Xu, Y.; Guo, Y.; Zhang, X.; et al. Tailoring highly ion-conductive and stabled PVDF-based solid electrolyte via surface coordination chemistry. Adv. Funct. Mater. 2025, 35, 2422461.
24. Cao, W.; Zhang, K.; Wang, J.; et al. Self-assembled silica-cellulose-ether ternary nanocomposite electrolytes for robust quasi-solid-state lithium metal batteries. Energy. Storage. Mater. 2025, 75, 104067.
25. Liu, Y.; Yu, Y.; Liu, Y.; et al. Biobased polymer electrolyte with plant cell wall-inspired architecture: biomimetic integration of cellulose-lignin for nonflammable cryogenic lithium batteries. Adv. Energy. Mater. 2025, 15, 2501737.
26. Mo, S.; An, H.; Liu, Q.; et al. Multistage bridge engineering for electrolyte and interface enables quasi-solid batteries to operate at -40 °C. Energy. Storage. Mater. 2024, 65, 103179.
27. Zhu, F.; Wang, J.; Zhang, Y.; et al. Low-temperature lithium metal batteries achieved by synergistically enhanced screening Li+ desolvation kinetics. Adv. Mater. 2025, 37, e2411601.
28. Zheng, Y.; Yang, N.; Gao, R.; et al. “Tree-Trunk” design for flexible quasi-solid-state electrolytes with hierarchical ion-channels enabling ultralong-life lithium-metal batteries. Adv. Mater. 2022, 34, e2203417.
29. Cheng, L.; Zhang, Y.; Li, D.; et al. Cu-MOF functionalized hydroxyapatite/bacterial cellulose composite separator enabling dendrite-free fast charging and enhanced thermal safety for high-loading graphite anode. Adv. Funct. Mater. 2026, 36, e15523.
30. Lin, R.; Jin, Y.; Zhang, X.; Li, Y.; Zhang, Y.; Xiong, Y. Hierarchical bulk-interface design of MOFs framework for polymer electrolyte towards ultra-stable quasi-solid-state Li metal batteries. Chem. Eng. J. 2024, 479, 147558.
31. Zhou, Q.; Oya, Y.; Chikada, T.; Zhang, W.; Xue, L.; Yan, Y. Preparation of Li2TiO3 by hydrothermal synthesis and its structure evolution under high energy Ar+ irradiation. J. Eur. Ceram. Soc. 2017, 37, 4955-61.
32. Sun, X.; Xu, W.; Zhang, X.; Lei, T.; Lee, S.; Wu, Q. ZIF-67@Cellulose nanofiber hybrid membrane with controlled porosity for use as Li-ion battery separator. J. Energy. Chem. 2021, 52, 170-80.
33. Xu, Y.; Chen, Z.; Wang, J.; et al. Design of quasi-metal-organic frameworks for solid polymer electrolytes enabling an ultra-stable interface with Li metal anode. Angew. Chem. Int. Ed. 2025, 64, e202416170.
34. Wu, X.; Liu, W.; Wu, H.; et al. Nanoporous ZIF-67 embedded polymers of intrinsic microporosity membranes with enhanced gas separation performance. J. Membrane. Sci. 2018, 548, 309-18.
35. Wang, F.; Kim, H.; Park, S.; Kee, C.; Kim, S.; Oh, I. Bendable and flexible supercapacitor based on polypyrrole-coated bacterial cellulose core-shell composite network. Compos. Sci. Technol. 2016, 128, 33-40.
36. Xu, T.; Du, H.; Liu, H.; et al. Advanced nanocellulose-based composites for flexible functional energy storage devices. Adv. Mater. 2021, 33, e2101368.
37. Zou, J.; Dong, H.; Wu, H.; et al. Laser-induced rapid construction of Co/N-doped honeycomb-like carbon networks as oxygen electrocatalyst used in zinc-air batteries. Carbon 2022, 200, 462-71.
38. Liu, P.; Xiao, L.; Chen, Y.; Chen, H. Highly enhanced electrochemical performances of LiNi0.815Co0.15Al0.035O2 by coating via conductively LiTiO2 for lithium-ion batteries. Ceram. Int. 2019, 45, 18398-405.
39. Xie, Y.; Wang, Q.; Gu, F.; Dai, K.; Shui, M.; Shu, J. The electro-chemical properties and intercalation mechanism of low strain Li2TiO3 as a high-performance anode material for lithium-ion batteries. J. Alloys. Compd. 2022, 893, 162348.
40. Sun, X.; Sun, S.; Gu, S.; et al. High-performance single atom bifunctional oxygen catalysts derived from ZIF-67 superstructures. Nano. Energy. 2019, 61, 245-50.
41. Gao, Q.; Li, J.; He, Y.; et al. High-performance antioxidant behavior of zeolitic imidazolate framework-67 at low filler content in silicone rubber. Polym. Degrad. Stabil. 2021, 190, 109622.
42. Zhu, W.; Zhang, L.; Liu, S.; et al. Enhanced CO2 electroreduction on neighboring Zn/Co monomers by electronic effect. Angew. Chem. Int. Ed. 2020, 59, 12664-8.
43. Yuan, B.; Cong, Z.; Cheng, Z.; et al. Bacteria cellulose framework-supported solid composite polymer electrolytes for ambient-temperature lithium metal batteries. Nanotechnology 2022, 33, 415401.
44. Song, X.; Ma, K.; Wang, J.; et al. Three-dimensional metal-organic framework@cellulose skeleton-reinforced composite polymer electrolyte for all-solid-state lithium metal battery. ACS. Nano. 2024, 18, 12311-24.
45. Brown, Z. L.; Jurng, S.; Nguyen, C. C.; Lucht, B. L. Effect of fluoroethylene carbonate electrolytes on the nanostructure of the solid electrolyte interphase and performance of lithium metal anodes. ACS. Appl. Energy. Mater. 2018, 1, 3057-62.
46. Li, L.; Wang, Z.; Li, H.; et al. ZIF-67 decorated PVDF fibers embedded in PEO and infiltrated with ionic liquid as composite polymer electrolyte for high performance secondary batteries using lithium metal as anode. J. Energy. Storage. 2025, 124, 116932.
47. Patil, R.; Kumar, N.; Bhattacharjee, S.; et al. Influence of catalase encapsulation on cobalt@nanoporous carbon with multiwall shell for supercapacitor and polyurethane synthesis using carbon dioxide. Chem. Eng. J. 2023, 453, 139874.
48. Wang, Y.; Liu, H.; Shi, Q.; et al. Single-atom titanium on mesoporous nitrogen, oxygen-doped carbon for efficient photo-thermal catalytic CO2 cycloaddition by a radical mechanism. Angew. Chem. Int. Ed. 2024, 63, e202404911.
49. Wang, R.; Yang, G.; Yang, T.; et al. Superionic conduction electrolyte through in situ structural transformation in electrochemical cell. Commun. Mater. 2025, 6, 811.






