REFERENCES
1. Ding, B.; Ding, Y.; Peng, J.; et al. Dopant-additive synergism enhances perovskite solar modules. Nature 2024, 628, 299-305.
2. Feng, Z.; Wang, Y.; Si, J.; et al. Multi‐site lead passivation via spatial configuration modulation of additives for efficient perovskite solar cells. Adv. Energy. Mater. 2025, 15, 2502409.
3. Mahmud, M. A.; Duong, T.; Peng, J.; et al. Origin of efficiency and stability enhancement in high‐performing mixed dimensional 2D‐3D perovskite solar cells: a review. Adv. Funct. Mater. 2021, 32, 2009164.
4. Zhang, J.; Tang, S.; Zhu, M.; et al. The role of grain boundaries in organic-inorganic hybrid perovskite solar cells and its current enhancement strategies: a review. Energy. Environ. Mater. 2024, 7, e12696.
5. Choi, H.; Liu, X.; Kim, H. I.; Kim, D.; Park, T.; Song, S. A facile surface passivation enables thermally stable and efficient planar perovskite solar cells using a novel IDTT‐based small molecule additive. Adv. Energy. Mater. 2021, 11, 2003829.
6. Xiong, S.; Hou, Z.; Zou, S.; et al. Direct observation on p- to n-type transformation of perovskite surface region during defect passivation driving high photovoltaic efficiency. Joule 2021, 5, 467-80.
7. Jiang, W.; Zhu, Y.; Liu, J.; et al. Improving the stability of wide bandgap perovskites: mechanisms, strategies, and applications in tandem solar cells. Adv. Mater. 2025, 37, 2418500.
8. Dong, W.; Qiao, W.; Xiong, S.; et al. Surface passivation and energetic modification suppress nonradiative recombination in perovskite solar cells. Nano. Micro. Lett. 2022, 14, 108.
9. Song, J.; Xie, H.; Lim, E. L.; Hagfeldt, A.; Bi, D. Progress and perspective on inorganic CsPbI2Br perovskite solar cells. Adv. Energy. Mater. 2022, 12, 2201854.
10. Huang, J.; Wang, H.; Jia, C.; et al. Advances in crystallization regulation and defect suppression strategies for all-inorganic CsPbX3 perovskite solar sells. Prog. Mater. Sci. 2024, 141, 101223.
11. Chen, P.; Xiao, Y.; Li, S.; et al. The promise and challenges of inverted perovskite solar cells. Chem. Rev. 2024, 124, 10623-700.
12. Huang, Y.; Zhang, W.; Xiong, Y.; et al. Recent advancements in ambient-air fabrication of perovskite solar cells. Exploration 2025, 5, 20240121.
13. Kang, Y.; Li, R.; Wang, A.; et al. Ionogel-perovskite matrix enabling highly efficient and stable flexible solar cells towards fully-R2R fabrication. Energy. Environ. Sci. 2022, 15, 3439-48.
14. Bellani, S.; Bartolotta, A.; Agresti, A.; et al. Solution-processed two-dimensional materials for next-generation photovoltaics. Chem. Soc. Rev. 2021, 50, 11870-965.
15. Kojima, A.; Teshima, K.; Shirai, Y.; Miyasaka, T. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J. Am. Chem. Soc. 2009, 131, 6050-1.
16. Green, M. A.; Dunlop, E. D.; Yoshita, M.; et al. Solar cell efficiency tables (version 66). Prog. Photovolt. 2025, 33, 795-810.
17. Mali, S. S.; Patil, J. V.; Steele, J. A.; Jung, Y. H.; Nazeeruddin, M. K.; Hong, C. K. Controlled crystallization and surface engineering of mixed-halide γ-CsPbI2Br inorganic perovskites via guanidinium iodide additive in air-processed perovskite solar cells. Mater. Today. 2023, 67, 33-45.
18. Shin, Y. S.; Song, J. W.; Lee, D. G.; et al. De-doping engineering for efficient and heat-stable perovskite solar cells. Joule 2025, 9, 101779.
19. Chen, S.; Liu, N.; Xu, F.; Wei, G. Challenges and strategies toward future stable perovskite photovoltaics. Solar. RRL. 2023, 7, 2300479.
20. Liu, Y.; Akin, S.; Hinderhofer, A.; et al. Stabilization of highly efficient and stable phase-pure FAPbI3 perovskite solar cells by molecularly tailored 2D‐overlayers. Angew. Chem. Int. Ed. 2020, 59, 15688-94.
21. Meng, J.; Gao, Y.; Hu, J.; et al. Deuterium-substituted cations enhance perovskite solar cell efficiency and stability. Joule 2025, 9, 102031.
22. Kang, B.; Yan, F. Emerging strategies for the large-scale fabrication of perovskite solar modules: from design to process. Energy. Environ. Sci. 2025, 18, 3917-54.
23. Perovskite solar cells that withstand photolysis and are stable under reverse bias. Nat. Mater. 2024, 23, 739-40.
24. Qiu, H.; Mativetsky, J. M. Elucidating the role of ion migration and band bending in perovskite solar cell function at grain boundaries via multimodal nanoscale mapping. Adv. Mater. Inter. 2021, 8, 2001992.
25. Li, X.; Xu, Z.; Zhao, R.; et al. Multifunctional interfacial molecular bridging strategy enables efficient and stable inverted perovskite solar cells. Adv. Mater. 2025, 37, 2508352.
26. Liu, W.; Chen, R.; Tan, Z.; et al. Buried interface engineering for scalable processing of high-performance inverted perovskite solar modules. Adv. Energy. Mater. 2024, 15, 2404374.
27. He, J.; Sheng, W.; Yang, J.; et al. Omnidirectional diffusion of organic amine salts assisted by ordered arrays in porous lead iodide for two-step deposited large-area perovskite solar cells. Energy. Environ. Sci. 2023, 16, 629-40.
28. Zhou, J.; Lv, J.; Tan, L.; et al. High‐efficiency large-area perovskite solar cells via a multifunctional crystallization regulating passivation additive. Adv. Mater. 2025, 37, 2502916.
29. Pandey, P.; Cho, S.; Bahadur, J.; et al. 4‐Phenylthiosemicarbazide molecular additive engineering for wide-bandgap sn halide perovskite solar cells with a record efficiency over 12.2%. Adv. Energy. Mater. 2024, 14, 2401188.
30. Wang, T.; Li, Y.; Cao, Q.; et al. Deep defect passivation and shallow vacancy repair via an ionic silicone polymer toward highly stable inverted perovskite solar cells. Energy. Environ. Sci. 2022, 15, 4414-24.
31. Yu, Y.; Liu, R.; Liu, C.; Shi, X. L.; Yu, H.; Chen, Z. G. Synergetic regulation of oriented crystallization and interfacial passivation enables 19.1% efficient wide-bandgap perovskite solar cells. Adv. Energy. Mater. 2022, 12, 2201509.
32. Chen, K.; Xiao, X.; Liu, J.; et al. Record‐efficiency printable hole-conductor-free mesoscopic perovskite solar cells enabled by the multifunctional schiff base derivative. Adv. Mater. 2024, 36, 2401319.
33. Wang, Q.; Zhu, J.; Zhao, Y.; et al. Cross‐layer all‐interface defect passivation with pre‐buried additive toward efficient all‐inorganic perovskite solar cells. Carbon. Energy. 2024, 6, e566.
34. Mcmeekin, D. P.; Holzhey, P.; Fürer, S. O.; et al. Intermediate-phase engineering via dimethylammonium cation additive for stable perovskite solar cells. Nat. Mater. 2022, 22, 73-83.
35. Wang, P.; Li, T.; Jin, Z.; et al. Simultaneous regulation of crystallization kinetics and Sn2+ oxidation suppression via moderate brønsted acid for efficient tin-based perovskite solar cells. Adv. Energy. Mater. 2025, 15, e01164.
36. Zeng, F.; Kong, W.; Liang, Y.; et al. Highly stable and efficient formamidinium-based 2D ruddlesden-popper perovskite solar cells via lattice manipulation. Adv. Mater. 2023, 35, 2306051.
37. Zhang, W.; Xing, C.; Song, W.; et al. Manipulation of interface recombination via multi-site passivator for efficient inverted perovskite solar cells and modules. Adv. Mater. 2025, 37, 2503954.
38. Cheng, W.; He, X.; Wang, J. G.; Tian, W.; Li, L. N‐(2‐aminoethyl) acetamide additive enables phase-pure and stable α‐FAPbI3 for efficient self-powered photodetectors. Adv. Mater. 2022, 34, 2208325.
39. Chen, H.; Liu, C.; Xu, J.; et al. Improved charge extraction in inverted perovskite solar cells with dual-site-binding ligands. Science 2024, 384, 189-93.
40. Wang, J.; Pan, Y.; Zhou, Z.; et al. Bimolecular crystallization modulation boosts the efficiency and stability of methylammonium-free tin-lead perovskite and all-perovskite tandem solar cells. Adv. Energy. Mater. 2024, 14, 2402171.
41. Wu, Z.; Kang, L.; Huang, T.; et al. Elevating perovskite efficiency via machine learning-assisted screening of passivators. Chem. Eng. J. 2024, 499, 156391.
42. Amoroso, D.; Nasti, G.; Sutter-fella, C. M.; Villone, M. M.; Maffettone, P. L.; Abate, A. The central role of colloids to explain the crystallization dynamics of halide perovskites: a critical review. Matter 2024, 7, 2399-430.
43. Pascual, J.; Flatken, M.; Félix, R.; et al. Fluoride chemistry in tin halide perovskites. Angew. Chem. Int. Ed. 2021, 60, 21583-91.
44. Treglia, A.; Olivati, A.; Romano, V.; et al. How shallow and deep defects drive carrier dynamics in tin-iodide perovskites. Adv. Energy. Mater. 2025, 15, 2404905.
45. Nakamura, T.; Yakumaru, S.; Truong, M. A.; et al. Sn(IV)-free tin perovskite films realized by in situ Sn(0) nanoparticle treatment of the precursor solution. Nat. Commun. 2020, 11, 3008.
46. Liu, J.; Wang, S.; Zhu, W.; Tang, Z.; Ding, L.; Hao, F. Highly symmetric Lewis base coordinated with Sn2+ for reducing voltage loss and retarding oxidation in tin-halide perovskite solar cells. Chem. Eng. J. 2023, 453, 139975.
47. Wang, S.; Yao, H.; Zhu, W.; et al. Stabilization of perovskite lattice and suppression of Sn2+/Sn4+ oxidation via formamidine acetate for high efficiency tin perovskite solar cells. Adv. Funct. Mater. 2023, 33, 2215041.
48. Geng, S.; Zhang, S.; Shen, N.; et al. Revealing collaborative effects of binary additives on regulating precursor crystallization toward highly efficient perovskite solar cells. Angew. Chem. Int. Ed. 2025, 64, e202424910.
49. Xie, L.; Liu, J.; Li, J.; et al. A deformable additive on defects passivation and phase segregation inhibition enables the efficiency of inverted perovskite solar cells over 24%. Adv. Mater. 2023, 35, 2302752.
50. Chen, J.; Luo, J.; Li, Y.; et al. Spatially isomeric fulleropyrrolidines enable controlled stacking of perovskite colloids for high-performance tin-based perovskite solar cells. Angew. Chem. Int. Ed. 2025, 64, e202420150.
51. Shen, X.; Gallant, B. M.; Holzhey, P.; et al. Chloride‐based additive engineering for efficient and stable wide-bandgap perovskite solar cells. Adv. Mater. 2023, 35, 2211742.
52. Tong, G.; Son, D. Y.; Ono, L. K.; et al. Scalable fabrication of >90 cm2 perovskite solar modules with >1000 h operational stability based on the intermediate phase strategy. Adv. Energy. Mater. 2021, 11, 2003712.
53. Xu, C.; Cheng, L.; Li, Z.; et al. Fast solidification and slow growth strategy for high-performance quasi‐2D perovskite solar cells. Adv. Energy. Mater. 2023, 13, 2300168.
54. Zhao, X.; Qiu, Y.; Wang, M.; et al. Regulation of buried interface through the rapid removal of PbI2·DMSO complex for enhancing light stability of perovskite solar cells. ACS. Energy. Lett. 2024, 9, 2659-69.
55. Tong, G.; Zhang, J.; Bu, T.; et al. Holistic strategies lead to enhanced efficiency and stability of hybrid chemical vapor deposition based perovskite solar cells and modules. Adv. Energy. Mater. 2023, 13, 2300153.
56. Li, J.; Dagar, J.; Shargaieva, O.; et al. 20.8% slot-die coated MAPbI3 perovskite solar cells by optimal DMSO‐content and age of 2‐ME based precursor inks. Adv. Energy. Mater. 2021, 11, 2003460.
57. Zhu, Y.; Liu, X.; Sui, X.; et al. Intermediate‐phase homogenization through intermolecular interactions toward reproducible fabrication of perovskite solar cells. Adv. Energy. Mater. 2025, 15, 2500536.
58. Pu, X.; Cao, Q.; He, X.; et al. Synergistic crystallization kinetics modulation and deep/shallow level defect passivation via an organometallic cobaltocenium salt toward high-performance inverted perovskite solar cells. Adv. Energy. Mater. 2024, 14, 2303972.
59. Liu, Z.; Ono, L. K.; Qi, Y. Additives in metal halide perovskite films and their applications in solar cells. J. Energy. Chem. 2020, 46, 215-28.
60. Xu, N.; Qi, X.; Shen, Z.; et al. Point defects in metal halide perovskites. Nat. Rev. Phys. 2025, 7, 554-64.
61. Ma, J.; Qin, M.; Li, P.; Han, L.; Zhang, Y.; Song, Y. Crystallization kinetics modulation and defect suppression of all-inorganic CsPbX3 perovskite films. Energy. Environ. Sci. 2022, 15, 413-38.
62. Shen, X.; Kang, K.; Yu, Z.; et al. Passivation strategies for mitigating defect challenges in halide perovskite light-emitting diodes. Joule 2023, 7, 272-308.
63. Isikgor, F. H.; Zhumagali, S.; T. Merino LV, De Bastiani M, Mcculloch I, De Wolf S. Molecular engineering of contact interfaces for high-performance perovskite solar cells. Nat. Rev. Mater. 2022, 8, 89-108.
64. Li, B.; Wang, X.; Zhang, T.; et al. Silicon nitride nanocomposites at the buried interface for stable perovskite solar cells. Nat. Photonics. 2026, 20, 280-6.
65. Zhang, H.; Pfeifer, L.; Zakeeruddin, S. M.; Chu, J.; Grätzel, M. Tailoring passivators for highly efficient and stable perovskite solar cells. Nat. Rev. Chem. 2023, 7, 632-52.
66. Park, J.; Walsh, A. Modeling grain boundaries in polycrystalline halide perovskite solar cells. Annu. Rev. Condens. Matter. Phys. 2021, 12, 95-109.
67. Su, G.; Yu, R.; Dong, Y.; et al. Crystallization regulation and defect passivation for efficient inverted wide-bandgap perovskite solar cells with over 21% efficiency. Adv. Energy. Mater. 2023, 14, 2303344.
68. Gu, H.; Zhu, A.; Xia, J.; et al. Nanoscale phase management of the 2D/3D heterostructure toward efficient perovskite solar cells. Sci. Bull. 2024, 69, 2853-61.
69. Zhang, H.; Tian, Q.; Xiang, W.; et al. Tailored cysteine-derived molecular structures toward efficient and stable inorganic perovskite solar cells. Adv. Mater. 2023, 35, 2301140.
70. Rana, P. J. S.; Febriansyah, B.; Koh, T. M.; et al. Molecular locking with all-organic surface modifiers enables stable and efficient slot-die-coated methyl-ammonium-free perovskite solar modules. Adv. Mater. 2023, 35, 2210176.
71. Zheng, L.; Shen, L.; Fang, Z.; et al. Reducing the surface reactivity of alkyl ammonium passivation molecules enables highly efficient perovskite solar cells. Adv. Energy. Mater. 2023, 13, 2301066.
72. Qu, S.; Li, Y.; Huang, H.; et al. Unveiling the mutual promotion mechanism of adjacent vacancy defects enables high-performance perovskite solar cells. Adv. Mater. 2025, 37, 2508643.
73. Yao, Z.; Xu, Z.; Zhao, W.; et al. Enhanced efficiency of inorganic CsPbI3-xBrx perovskite solar cell via self-regulation of antisite defects. Adv. Energy. Mater. 2021, 11, 2100403.
74. Liu, B.; Ren, X.; Li, R.; et al. Stabilizing top interface by molecular locking strategy with polydentate chelating biomaterials toward efficient and stable perovskite solar cells in ambient air. Adv. Mater. 2024, 36, 2312679.
75. Li, M.; Ma, X.; Fu, J.; et al. Molecularly tailored perovskite/poly(3-hexylthiophene) interfaces for high-performance solar cells. Energy. Environ. Sci. 2024, 17, 5513-20.
76. Chen, G.; Gan, Y.; Wang, S.; et al. Dicyandiamide-driven tailoring of the n-value distribution and interface dynamics for high-performance ACI 2D perovskite solar cells. Nano. Micro. Lett. 2025, 17, 305.
77. Wu, Y.; Wang, Q.; Chen, Y.; Qiu, W.; Peng, Q. Stable perovskite solar cells with 25.17% efficiency enabled by improving crystallization and passivating defects synergistically. Energy. Environ. Sci. 2022, 15, 4700-9.
78. Guan, H.; Fu, S.; Zeng, G.; et al. Efficient 1.77 eV-bandgap perovskite and all-perovskite tandem solar cells enabled by long-alkyl phosphonic acid. Energy. Environ. Sci. 2024, 17, 8219-27.
79. Stone, K. H.; Gold-parker, A.; Pool, V. L.; et al. Transformation from crystalline precursor to perovskite in PbCl2-derived MAPbI3. Nat. Commun. 2018, 9, 3458.
80. Kim, M.; Kim, G.; Lee, T. K.; et al. Methylammonium chloride induces intermediate phase stabilization for efficient perovskite solar cells. Joule 2019, 3, 2179-92.
81. Lim, J.; Kim, J.; Davies-jones, J.; et al. Benign methylformamidinium byproduct induced by cation heterogeneity inhibits local formation of δ-phase perovskites. Energy. Environ. Sci. 2024, 17, 9134-43.
82. Ma, Y.; Cai, H.; Liu, Y.; et al. Alleviation of precursor degradation induced by DMF/DMSO mixture for enhanced performance of perovskite solar cells. Angew. Chem. Int. Ed. 2025, 64, e202504253.
83. Yang, T.; Gao, L.; Lu, J.; et al. One-stone-for-two-birds strategy to attain beyond 25% perovskite solar cells. Nat. Commun. 2023, 14, 839.
84. Su, Y.; Ding, J.; Zhang, Z.; et al. Chemical inhibition of light-induced decomposition by hindered amine for efficient and stable perovskite solar cells. eScience 2026, 6, 100451.
85. Zhang, N.; Li, T.; Wang, C.; et al. Host-guest complexation strategy for passivating Pb-dimer related defects in perovskite photovoltaics. Adv. Funct. Mater. 2023, 33, 2300830.
86. Ahmed, R.; Rehman, S.; Chen, Z.; Ye, F.; Ren, X. Ligand assisted hydrogen bonding: a game-changer in lead passivation and stability in perovskite solar cells. Angew. Chem. Int. Ed. 2024, 137, e202418763.
87. Wang, Y.; Cao, Q.; Xiang, X.; Zhou, J. Symmetric polar molecule optimized buried interface for stable flexible perovskite solar cells. ACS. Sustain. Chem. Eng. 2024, 12, 18265-75.
88. Wang, K.; Yu, B.; Lin, C.; Yao, R.; Yu, H.; Wang, H. Constructing stable perovskite with small molecule bridge interface passivation. Adv. Energy. Mater. 2025, 15, 2405571.
89. Tong, X.; Ma, Y.; Xie, L.; et al. Regulating spatial charge distribution of multisite passivating additives enables stable perovskite solar cells. Adv. Funct. Mater. 2025, 35, e11458.
90. Xu, T.; Xiang, W.; Ru, X.; et al. Enhancing stability and efficiency of inverted inorganic perovskite solar cells with in-situ interfacial cross-linked modifier. Adv. Mater. 2024, 36, 2312237.
91. Cao, S.; Luo, S.; Zheng, T.; et al. Hybrid self-assembled molecular interlayers for efficient and stable inverted perovskite solar cells. Adv. Energy. Mater. 2025, 15, 2405367.
92. Wei, H.; Chen, R.; Yang, Y.; et al. Dihydrazide-mediated crystal engineering and precursor anti-aging for efficient and stable perovskite solar cells and modules. Adv. Funct. Mater. 2025, 36, e16987.
93. Liu, C.; Su, H.; Pu, Y.; et al. 3D polydentate complexing agents for passivating defects and modulating crystallinity for high-performance perovskite solar cells. Adv. Funct. Mater. 2023, 33, 2212577.
94. Cheng, M.; Duan, Y.; Zhang, D.; et al. Tailoring buried interface and minimizing energy loss enable efficient narrow and wide bandgap inverted perovskite solar cells by aluminum glycinate based organometallic molecule. Adv. Mater. 2025, 37, 2419413.
95. Xie, Z.; Duan, Y.; Cheng, M.; et al. High-efficiency perovskite solar cells enabled by guanylation reaction for removing MACl residual and in-situ forming 2D perovskite. Angew. Chem. Int. Ed. 2025, 64, e202419070.
96. Xie, H.; Wang, Z.; Chen, Z.; et al. Decoupling the effects of defects on efficiency and stability through phosphonates in stable halide perovskite solar cells. Joule 2021, 5, 1246-66.
97. Liu, Y.; Xu, H.; Ji, S.; et al. Thiourea derivative induced crystallization for enhanced efficiency and stability of perovskite solar cells over 25%. J. Energy. Chem. 2025, 108, 109-17.
98. Wang, X.; Wang, Y.; Chen, Y.; Liu, X.; Zhao, Y. Efficient and stable CsPbI3 inorganic perovskite photovoltaics enabled by crystal secondary growth. Adv. Mater. 2021, 33, 2103688.
99. Pasha, A.; Pramanik, P.; George, J. K.; et al. Cationic and anionic vacancy healing for suppressed halide exchange and phase segregation in perovskite solar cells. ACS. Energy. Lett. 2023, 8, 3081-7.
100. Cheng, H.; Liu, C.; Zhuang, J.; et al. KBF4 additive for alleviating microstrain, improving crystallinity, and passivating defects in inverted perovskite solar cells. Adv. Funct. Mater. 2022, 32, 2204880.
101. Zhu, J.; He, B.; Zhang, W.; et al. Defect‐dependent crystal plane control on inorganic CsPbBr3 film by selectively anchoring (pseudo-) halide anions for 1.650 V voltage perovskite solar cells. Adv. Funct. Mater. 2022, 32, 2206838.
102. Zhao, W.; Guo, P.; Su, J.; et al. Synchronous passivation of defects with low formation energies via terdentate anchoring enabling high performance perovskite solar cells with efficiency over 24%. Adv. Funct. Mater. 2022, 32, 2200534.
103. Zhuang, J.; Liu, C.; Kang, B.; et al. Rapid surface reconstruction in air-processed perovskite solar cells by blade coating. Adv. Mater. 2023, 36, 2309869.
104. Qiao, X.; Zhu, R.; Yan, D.; et al. Multi‐point collaborative passivation of surface defects for efficient and stable perovskite solar cells. Adv. Funct. Mater. 2024, 34, 2409852.
105. Park, N.; Zhu, K. Scalable fabrication and coating methods for perovskite solar cells and solar modules. Nat. Rev. Mater. 2020, 5, 333-50.
106. Liu, J.; Zheng, D.; Wang, K.; et al. Evolutionary manufacturing approaches for advancing flexible perovskite solar cells. Joule 2024, 8, 944-69.
107. Li, C.; Vincze, A.; Park, H.; et al. Anchoring ligand engineering enables highly stable MA-free perovskite solar cells with a minimal VOC deficit of 0.32 V. Energy. Environ. Sci. 2025, 18, 7660-8.
108. Zhou, W.; Cai, Y.; Wan, S.; et al. A universal strategy for defects and interface management enables highly efficient and stable inverted perovskite solar cells. Energy. Environ. Sci. 2025, 18, 3828-38.
109. Song, Z.; Zou, Y.; Gao, Y.; et al. Buried and bulk synergistic engineering enables high-performance inverted 2D/3D perovskite solar cells. Energy. Environ. Sci. 2025, 18, 3740-9.
110. Kosar, S.; Winchester, A. J.; Doherty, T. A. S.; et al. Unraveling the varied nature and roles of defects in hybrid halide perovskites with time-resolved photoemission electron microscopy. Energy. Environ. Sci. 2021, 14, 6320-8.
111. Ansari, F.; Zheng, L.; Pfeifer, L.; et al. Dopamine dopes the performance of perovskite solar cells. Adv. Mater. 2025, 37, 2501075.
112. Yang, H.; Zhao, J.; Ren, X.; et al. Bifunctional passivation by lewis-base molecules for efficient printable mesoscopic perovskite solar cells. J. Energy. Chem. 2024, 96, 177-84.
113. Xiao, G.; Meng, R.; Yang, S.; Cao, J.; Tang, Y. Cerium oxide nanoparticle as interfacial modifier for efficient and UV-stable perovskite solar cells. Chem. Eng. J. 2023, 462, 142047.
114. Fahim, M.; Firdous, I.; Daoud, W. A. Cascade bridge interfacial design for stable and sustainable flexible perovskite solar cells. SusMat 2025, 5, e70016.
115. Luo, Z.; Tang, L.; Zeng, L.; et al. Albendazole passivation in inverted wide‐bandgap perovskite solar cells toward efficient perovskite/CuInGaSe2 tandem photovoltaics. Adv. Mater. 2025, 37, e05597.
116. Chen, J.; Wang, X.; Wang, T.; et al. Determining the bonding-degradation trade-off at heterointerfaces for increased efficiency and stability of perovskite solar cells. Nat. Energy. 2025, 10, 181-90.
117. Liu, S.; Li, J.; Xiao, W.; et al. Buried interface molecular hybrid for inverted perovskite solar cells. Nature 2024, 632, 536-42.
118. Gao, M.; Ou, Z.; Wang, C.; et al. Multifunctional buried molecule-bridge for high-performance inverted perovskite solar cells. Adv. Mater. 2025, 38, e14273.
119. Li, L.; Xue, T.; Yuan, F.; et al. Buried interface chelating molecular bridge strategy enables highly efficient and stable inverted perovskite solar cells. Adv. Mater. 2025, 38, e18406.
120. Park, B.; Kedem, N.; Kulbak, M.; et al. Understanding how excess lead iodide precursor improves halide perovskite solar cell performance. Nat. Commun. 2018, 9, 3301.
121. Wang, H.; Wang, Z.; Yang, Z.; et al. Ligand‐modulated excess PbI2 nanosheets for highly efficient and stable perovskite solar cells. Adv. Mater. 2020, 32, 2000865.
122. Liang, J.; Wang, T.; Jia, Y.; et al. Turning waste into treasure: pretreatment strategy for promoting secondary grain growth by reusing excess lead iodide in perovskite solar cells. Adv. Mater. 2025, 37, 2508211.
123. Gao, Y.; Ren, F.; Sun, D.; et al. Elimination of unstable residual lead iodide near the buried interface for the stability improvement of perovskite solar cells. Energy. Environ. Sci. 2023, 16, 2295-303.
124. Wang, K. L.; Li, M.; Lou, Y. H.; et al. Aniline sulfonic acid induced uniform perovskite film for large-scale photovoltaics. Adv. Energy. Mater. 2023, 13, 2203471.
125. Holovský, J.; Peter, Amalathas. A.; Landová, L.; et al. Lead halide residue as a source of light-induced reversible defects in hybrid perovskite layers and solar cells. ACS. Energy. Lett. 2019, 4, 3011-7.
126. Fu, S.; Sun, N.; Chen, H.; et al. On-demand formation of Lewis bases for efficient and stable perovskite solar cells. Nat. Nanotechnol. 2025, 20, 772-8.
127. Zhao, Y.; Ma, F.; Qu, Z.; et al. Inactive (PbI2)2 RbCl stabilizes perovskite films for efficient solar cells. Science 2022, 377, 531-4.
128. Zhang, Z.; Huang, Y.; Wang, C.; et al. Green-antisolvent-regulated distribution of p-type self-doping enables tin perovskite solar cells with an efficiency of over 14%. Energy. Environ. Sci. 2023, 16, 3430-40.
129. Xu, J.; Chen, H.; Grater, L.; et al. Anion optimization for bifunctional surface passivation in perovskite solar cells. Nat. Mater. 2023, 22, 1507-14.
130. Azam, M.; Du, T.; Wan, Z.; et al. Dual functionality of charge extraction and interface passivation by self-assembled monolayers in perovskite solar cells. Energy. Environ. Sci. 2024, 17, 6974-7016.
131. Pu, Y.; Dai, Z.; Zhou, Y.; et al. Machine learning co-pilot for screening of organic molecular additives for perovskite solar cells. arXiv 2024, 2412.14109.
132. Xiong, S.; Hou, Z.; Dong, W.; et al. Additive-induced synergies of defect passivation and energetic modification toward highly efficient perovskite solar cells. Adv. Energy. Mater. 2021, 11, 2101394.
133. Hu, F.; Chen, C. H.; Teng, T. Y.; et al. Constructing charge bridge path for high-performance tin perovskite photovoltaics. Adv. Energy. Mater. 2024, 14, 2302926.
134. Li, D.; Huang, Y.; Ma, R.; et al. Surface regulation with polymerized small molecular acceptor towards efficient inverted perovskite solar cells. Adv. Energy. Mater. 2023, 13, 2204247.
135. Azmi, R.; Zhumagali, S.; Bristow, H.; et al. Moisture‐resilient perovskite solar cells for enhanced stability. Adv. Mater. 2023, 36, 2211317.
136. Zhang, X.; Pascual, J.; Li, Z.; et al. Buried hole-selective interface engineering for high-efficiency tin-lead perovskite solar cells with enhanced interfacial chemical stability. Sci. Bull. 2025, 70, 556-62.
137. Sharma, B.; Garai, R.; Afroz, M. A.; et al. Enhancing light utilization efficiency of semi-transparent perovskite solar cells via tailored interfacial engineering. Adv. Energy. Mater. 2024, 14, 2402473.
138. Zhu, H.; Teale, S.; Lintangpradipto, M. N.; et al. Long-term operating stability in perovskite photovoltaics. Nat. Rev. Mater. 2023, 8, 569-86.
139. Degani, M.; Pallotta, R.; Pica, G.; et al. Compositional gradient of mixed halide 2D perovskite interface boosts outdoor stability of highly efficient perovskite solar cells. Adv. Energy. Mater. 2024, 15, 2404469.
140. Kim, H.; Choi, K.; Yoon, G. W.; et al. Modulating molecular interaction of zwitterion toward rational interface engineering of perovskite solar cells. Adv. Energy. Mater. 2024, 14, 2401263.
141. Kim, S. G.; Le, T. H.; De, Monfreid. T.; Goubard, F.; Bui, T. T.; Park, N. G. Capturing mobile lithium ions in a molecular hole transporter enhances the thermal stability of perovskite solar cells. Adv. Mater. 2021, 33, 2007431.
142. Qin, Z.; Chen, Y.; Wang, X.; et al. Zwitterion‐functionalized SnO2 substrate induced sequential deposition of black-phase FAPbI3 with rearranged PbI2 residue. Adv. Mater. 2022, 34, 2203143.
143. Yuan, Y.; Yan, G.; Hong, R.; Liang, Z.; Kirchartz, T. Quantifying efficiency limitations in all‐inorganic halide perovskite solar cells. Adv. Mater. 2022, 34, 2108132.
144. Tian, J.; Xue, Q.; Yao, Q.; Li, N.; Brabec, C. J.; Yip, H. L. Inorganic halide perovskite solar cells: progress and challenges. Adv. Energy. Mater. 2020, 10, 2000183.
145. Liu, T.; Zhang, J.; Qin, M.; et al. Modifying surface termination of CsPbI3 grain boundaries by 2D perovskite layer for efficient and stable photovoltaics. Adv. Funct. Mater. 2021, 31, 2009515.
146. Yu, B.; Shi, J.; Tan, S.; et al. Efficient (>20 %) and stable all-inorganic cesium lead triiodide solar cell enabled by thiocyanate molten salts. Angew. Chem. Int. Ed. 2021, 60, 13436-43.
147. Wang, P.; Wang, H.; Mao, Y.; et al. Organic ligands armored ZnO enhances efficiency and stability of CsPbI2Br perovskite solar cells. Adv. Sci. 2020, 7, 2000421.
148. Niu, T.; Zhu, W.; Zhang, Y.; et al. D-A-π-A-D-type dopant-free hole transport material for low-cost, efficient, and stable perovskite solar cells. Joule 2021, 5, 249-69.
149. Zhang, W.; Xiong, J.; Li, J.; Daoud, W. A. Organic dye passivation for high-performance all-inorganic CsPbI1.5Br1.5 perovskite solar cells with efficiency over 14%. Adv. Energy. Mater. 2020, 11, 2003585.
150. Wang, B.; Li, H.; Dai, Q.; et al. Robust molecular dipole-enabled defect passivation and control of energy‐level alignment for high-efficiency perovskite solar cells. Angew. Chem. Int. Ed. 2021, 60, 17664-70.
151. Sung, S. J.; Im, J.; Kim, G.; et al. Molecular engineering for function-tailored interface modifier in high-performance perovskite solar cells. Adv. Energy. Mater. 2022, 12, 2200758.
152. Liu, S.; Sun, Z.; Lei, X.; et al. Stable surface contact with tailored alkylamine pyridine derivatives for high-performance inverted perovskite solar cells. Adv. Mater. 2024, 37, 2415100.
153. Yang, Q.; Liu, X.; Yu, S.; et al. Hydroxylated non-fullerene acceptor for highly efficient inverted perovskite solar cells. Energy. Environ. Sci. 2021, 14, 6536-45.
154. Guan, H.; Zhou, S.; Fu, S.; et al. Regulating crystal orientation via ligand anchoring enables efficient wide-bandgap perovskite solar cells and tandems. Adv. Mater. 2023, 36, 2307987.
155. Liu, D.; Chen, C.; Wang, X.; et al. Enhanced quasi-fermi level splitting of perovskite solar cells by universal dual-functional polymer. Adv. Mater. 2023, 36, 2310962.
156. Dong, Y.; Rombach, F. M.; Min, G.; et al. Dopant-induced interactions in spiro-OMeTAD: advancing hole transport for perovskite solar cells. Mater. Sci. Eng. R. Rep. 2025, 162, 100875.
157. Shen, L.; Song, P.; Jiang, K.; et al. Ultrathin polymer membrane for improved hole extraction and ion blocking in perovskite solar cells. Nat. Commun. 2024, 15, 10908.
158. Cai, Y.; Bai, Z.; Chen, C.; et al. Machine learning prediction of small molecule passivators and their impacts on the passivation and photocatalytic performance of organic-inorganic hybrid perovskite interfaces. Energy. Mater. 2025, 5, 500043.
159. Liu, J.; Lv, H.; Wang, P.; et al. Synergistic machine learning and DFT screening strategy: accelerating discovery of efficient perovskite passivators. J. Energy. Chem. 2026, 112, 56-63.
160. Lyu, Y.; Zhou, Y.; Zhang, Y.; et al. Fingerprinting organic molecules for the inverse design of two-dimensional hybrid perovskites with target energetics. Sci. Adv. 2026, 12, eaeb4144.
161. Odabaşı, Ç.; Yıldırım, R. Performance analysis of perovskite solar cells in 2013-2018 using machine-learning tools. Nano. Energy. 2019, 56, 770-91.
162. Yang, A.; Sun, Y.; Zhang, J.; et al. Enhancing power conversion efficiency of perovskite solar cells through machine learning guided experimental strategies. Adv. Funct. Mater. 2024, 35, 2410419.
163. Liu, T.; Evans, N.; Ji, K.; et al. Disentangling environmental effects on perovskite solar cell performance via interpretable machine learning. ACS. Energy. Lett. 2026, 11, 1609-17.
164. Liao, J. M.; Chen, Y. H.; Lee, H. W.; et al. Advanced high-throughput rational design of porphyrin-sensitized solar cells using interpretable machine learning. Adv. Sci. 2024, 11, 2407235.
165. Pu, Y.; Dai, Z.; Zhou, Y.; et al. Data‐driven molecular encoding for efficient screening of organic additives in perovskite solar cells. Adv. Funct. Mater. 2025, 36, e06672.
166. Sanimu, S. N.; Yang, H. Y.; Kandel, J.; et al. Machine learning-assisted fabrication of PCBM‐perovskite solar cells with nanopatterned TiO2 layer. Energy. Environ. Mater. 2023, 7, e12676.
167. Jiang, S.; Wu, C. C.; Li, F.; et al. Machine learning (ML)‐assisted optimization doping of KI in MAPbI3 solar cells. Rare. Metals. 2020, 40, 1698-707.
168. Miftahullatif, E. B.; Pethe, S. D.; Low, A. K. Y.; et al. Machine-learning-driven in-device optimization of all-printed perovskite solar cells. ACS. Energy. Lett. 2025, 10, 3952-61.
169. Lou, Q.; Wang, J.; Nie, Z.; et al. Prediction and fine screening of small molecular passivation materials for high-efficiency perovskite solar cells via an enhanced machine learning workflow. Adv. Funct. Mater. 2025, 35, e11549.
170. Zhang, J.; Wu, J.; Le, Corre. V. M.; Hauch, J. A.; Zhao, Y.; Brabec, C. J. Advancing perovskite photovoltaic technology through machine learning‐driven automation. InfoMat 2025, 7, e70005.
171. Tao, Q.; Xu, P.; Li, M.; Lu, W. Machine learning for perovskite materials design and discovery. NPJ. Comput. Mater. 2021, 7, 23.
172. Zhang, J.; Le, Corre. V. M.; Wu, J.; et al. Autonomous optimization of air‐processed perovskite solar cell in a multidimensional parameter space. Adv. Energy. Mater. 2025, 15, 2404957.
