REFERENCES

1. Zheng, J.; Liang, K.; Shi, K.; Qiu, Y. In situ synthesis and electrochemical properties of Fe/Li2O as a high-capacity cathode prelithiation additive for lithium ion batteries. Int. J. Electrochem. Sci. 2019, 14, 5305-16.

2. Sun, Y.; Lee, H.; Seh, Z. W.; et al. High-capacity battery cathode prelithiation to offset initial lithium loss. Nat. Energy. 2016, 1, 15008.

3. Peled, E.; Menkin, S. Review-SEI: past, present and future. J. Electrochem. Soc. 2017, 164, A1703-19.

4. Liu, X.; Liu, J.; Peng, J.; et al. Addressing the initial lithium loss of lithium ion batteries by introducing pre-lithiation reagent Li5FeO4/C in the cathode side. Electrochim. Acta. 2024, 481, 143918.

5. Kobayashi, H.; Nakamura, Y.; Nakayama, M.; Kodaki, S.; Matsuo, R.; Honma, I. Metastable cubic structure exceeds capacity limit of antifluorite Li5FeO4 cathode using small polarized oxygen redox. Adv. Energy. Mater. 2023, 13, 2203441.

6. Zhan, R.; Wang, X.; Chen, Z.; Seh, Z. W.; Wang, L.; Sun, Y. Promises and challenges of the practical implementation of prelithiation in lithium-ion batteries. Adv. Energy. Mater. 2021, 11, 2101565.

7. Lee, W.; Lee, H.; Byeon, Y.; et al. Modulating anion redox reactions and structural evolution through Fe-substitution in Li6CoO4 hyper-lithiated sacrificial cathodes. Adv. Energy. Mater. 2023, 13, 2302316.

8. Jin, L.; Shen, C.; Shellikeri, A.; et al. Progress and perspectives on pre-lithiation technologies for lithium ion capacitors. Energy. Environ. Sci. 2020, 13, 2341-62.

9. Sun, C.; Zhang, X.; Li, C.; Wang, K.; Sun, X.; Ma, Y. Recent advances in prelithiation materials and approaches for lithium-ion batteries and capacitors. Energy. Storage. Mater. 2020, 32, 497-516.

10. Zou, K.; Deng, W.; Cai, P.; et al. Prelithiation/presodiation techniques for advanced electrochemical energy storage systems: concepts, applications, and perspectives. Adv. Funct. Mater. 2021, 31, 2005581.

11. Wen, N.; Li, J.; Zhang, Z. Advancements in anti-fluorite cathode prelithiation materials for lithium-ion batteries: fundamental research and practical application. Small. Methods. 2025, 9, e01164.

12. Chen, Y.; Yang, M.; Zhu, Y.; et al. Converting Li-rich layered oxide cathode into non-shrinking sacrificial prelithiation agent. Adv. Mater. 2025, 37, e09827.

13. Su, X.; Lin, C.; Wang, X.; et al. A new strategy to mitigate the initial capacity loss of lithium ion batteries. J. Power. Sources. 2016, 324, 150-7.

14. Johnson, C. S.; Kang, S.; Vaughey, J. T.; Pol, S. V.; Balasubramanian, M.; Thackeray, M. M. Li2O removal from Li5FeO4: a cathode precursor for lithium-ion batteries. Chem. Mater. 2010, 22, 1263-70.

15. Zhang, L.; Dose, W. M.; Vu, A. D.; Johnson, C. S.; Lu, W. Mitigating the initial capacity loss and improving the cycling stability of silicon monoxide using Li5FeO4. J. Power. Sources. 2018, 400, 549-55.

16. Zhu, B.; Zhang, W.; Wang, Q.; et al. Understanding the air-exposure degradation chemistry of the sacrificial cathode additive Li5FeO4 for Li-ion batteries. Adv. Funct. Mater. 2024, 34, 2315010.

17. Wen, N.; Li, J.; Zhu, B.; Guo, J.; Zhang, Z. Unraveling the delithiation mechanism of air-stabilized fluorinated lithium iron oxide pre-lithiation material. Chem. Eng. J. 2024, 497, 154536.

18. Zhu, B.; Wen, N.; Wang, J.; Wang, Q.; Zheng, J.; Zhang, Z. Defect engineering of air-stable Li5FeO4 towards an ultra-high capacity cathode prelithiation additive. Chem. Sci. 2024, 15, 12879-88.

19. Liu, C.; Zhang, H.; Zhou, W.; et al. Air-stable Li5FeO4 additive enabled by carbon coating for energy-dense lithium-ion batteries. Nat. Commun. 2025, 16, 7694.

20. Zhu, B.; Zhang, W.; Li, Z.; Wang, Q.; Wen, N.; Zhang, Z. Effect of the N,S-codoped carbon layer on the rate performance of air-stable lithium iron oxide prelithiation additives. ACS. Appl. Mater. Interfaces. 2023, 15, 45290-9.

21. Zhu, B.; Zhang, W.; Li, Z.; et al. “Fe-locking” effect by g-C3N4 stabilizing lithium iron oxide pre-lithiation additives. J. Power. Sources. 2024, 592, 233944.

22. Zhu, B.; Zhang, W.; Wen, N.; et al. Structurally modulated advanced Na-doped antifluorite-based pre-lithiation reagents towards superior lithium compensation. Chem. Eng. J. 2025, 509, 161529.

23. Zhu, B.; Zhang, W.; Li, S.; et al. Lattice modulation on air-stable fe-based prelithiation materials with high capacity via triggering anionic redox activity. ACS. Appl. Mater. Interfaces. 2025, 17, 12448-57.

24. Göbbels, D.; Meyer, G. Aufbau und Abbau von (NH4)[BF4] und H3N-BF3. Z. anorg. allg. Chem. 2002, 628, 1799-805. https://onlinelibrary.wiley.com/doi/10.1002/1521-3749(200208)628:8%3C1799::AID-ZAAC1799%3E3.0.CO;2-L (accessed 2026-10-23).

25. Chen, Y.; Freunberger, S. A.; Peng, Z.; Bardé, F.; Bruce, P. G. Li-O2 battery with a dimethylformamide electrolyte. J. Am. Chem. Soc. 2012, 134, 7952-7.

26. Zhu, Y.; Xu, R.; Zheng, Y.; et al. Unravelling the oxygen evolution mechanism of lithium-rich antifluorite prelithiation agent based on anionic oxidation. Angew. Chem. Int. Ed. 2025, 64, e202502126.

27. Zhu, X.; Schulli, T.; Wang, L. Stabilizing high-voltage cathode materials for next-generation Li-ion batteries. Chem. Res. Chin. Univ. 2020, 36, 24-32.

Energy Materials
ISSN 2770-5900 (Online)
Follow Us

Portico

All published articles are preserved here permanently:

https://www.portico.org/publishers/oae/

Portico

All published articles are preserved here permanently:

https://www.portico.org/publishers/oae/