REFERENCES

1. Wen, X.; Chen, C.; Lu, S.; et al. Vapor transport deposition of antimony selenide thin film solar cells with 7.6% efficiency. Nat. Commun. 2018, 9, 2179.

2. Li, Z.; Liang, X.; Li, G.; et al. 9.2%-efficient core-shell structured antimony selenide nanorod array solar cells. Nat. Commun. 2019, 10, 125.

3. Wang, L.; Li, D.; Li, K.; et al. Stable 6%-efficient Sb2Se3 solar cells with a ZnO buffer layer. Nat. Energy. 2017, 2, 17046.

4. Chen, C.; Li, K.; Chen, S.; et al. Efficiency improvement of Sb2Se3 solar cells via grain boundary inversion. ACS. Energy. Lett. 2018, 3, 2335-41.

5. Zhao, Y.; Wang, S.; Li, C.; et al. Regulating deposition kinetics via a novel additive-assisted chemical bath deposition technology enables fabrication of 10.57%-efficiency Sb2Se3 solar cells. Energy. Environ. Sci. 2022, 15, 5118-28.

6. Zhu, P.; Chen, C.; Dai, J.; et al. Toward the commercialization of perovskite solar modules. Adv. Mater. 2024, 36, e2307357.

7. Shah, U. A.; Wang, A.; Irfan, Ullah. M.; et al. A deep dive into Cu2ZnSnS4 (CZTS) solar cells: a review of exploring roadblocks, breakthroughs, and shaping the future. Small 2024, 20, e2310584.

8. Wijesinghe, U.; Longo, G.; Hutter, O. S. Defect engineering in antimony selenide thin film solar cells. Energy. Adv. 2023, 2, 12-33.

9. Ma, Y.; Tang, B.; Lian, W.; et al. Efficient defect passivation of Sb2Se3 film by tellurium doping for high performance solar cells. J. Mater. Chem. A. 2020, 8, 6510-6.

10. Wang, Z.; Bae, S.; Baljozović, M.; et al. One-step hydrothermal synthesis of Sn-doped Sb2Se3 for solar hydrogen production. ACS. Catal. 2024, 14, 9877-86.

11. Ramírez-Velasco, S.; González-Castillo, J.; Ayala-Mató, F.; Hernández-Calderón, V.; Jiménez-Olarte, D.; Vigil-Galán, O. Back contact modification in Sb2Se3 solar cells: the effect of a thin layer of MoSe2. Thin. Solid. Films. 2022, 751, 139227.

12. Zhao, Q.; Che, B.; Wang, H.; et al. Crystal reconstruction and defect healing enabled high-quality Sb2Se3 films for solar cell applications. J. Mater. Chem. A. 2024, 12, 11524-34.

13. Jakomin, R.; Rampino, S.; Spaggiari, G.; Pattini, F. Advances on Sb2Se3 solar cells fabricated by physical vapor deposition techniques. Solar 2023, 3, 566-95.

14. Zhao, Q.; Tang, R.; Yang, S.; Chen, T. Post-treatment strategies toward high-quality Sb2Se3 thin films in photovoltaic applications. Adv. Sci. 2025, 12, e11387.

15. Che, B.; Cai, Z.; Xu, H.; et al. Post-deposition treatment of Sb2Se3 enables defect passivation and increased carrier transport dimension for efficient solar cell application. Angew. Chem. Int. Ed. 2025, 64, e202425639.

16. Otavio Mendes, J.; Merenda, A.; Wilson, K.; Fraser Lee, A.; Della Gaspera, E.; van Embden, J. Substrate morphology directs (001) Sb2Se3 thin film growth by crystallographic orientation filtering. Small 2024, 20, e2302721.

17. Liang, X.; Feng, Y.; Dang, W.; et al. High-efficiency flexible Sb2Se3 solar cells by back interface and absorber bulk deep-level trap engineering. ACS. Energy. Lett. 2022, 8, 213-21.

18. Pasini, S.; Spoltore, D.; Parisini, A.; et al. Innovative back-contact for Sb2Se3-based thin film solar cells. Sol. Energy. 2023, 249, 414-23.

19. Guo, H.; Huang, S.; Zhu, H.; et al. Enhancement in the efficiency of Sb2Se3 solar cells by triple function of lithium hydroxide modified at the back contact interface. Adv. Sci. 2023, 10, e2304246.

20. Hoang, V.; Lee, J.; Lim, G.; et al. Interface engineering of co-evaporated Sb2Se3 solar cells using an ALD SnOx interlayer. EES. Sol. 2025, 1, 990-1003.

21. Spalatu, N.; Krautmann, R.; Katerski, A.; et al. Screening and optimization of processing temperature for Sb2Se3 thin film growth protocol: Interrelation between grain structure, interface intermixing and solar cell performance. Sol. Energy. Mater. Sol. Cells. 2021, 225, 111045.

22. Hanifehpour, Y.; Joo, S. W.; Min, B. K. Lu3+/Yb3+ and Lu3+/Er3+ co-doped antimony selenide nanomaterials: synthesis, characterization, and electrical, thermoelectrical, and optical properties. Nanoscale. Res. Lett. 2013, 8, 141.

23. Parnicka, P.; Mazierski, P.; Grzyb, T.; et al. Influence of the preparation method on the photocatalytic activity of Nd-modified TiO2. Beilstein. J. Nanotechnol. 2018, 9, 447-59.

24. Alemi, A.; Hanifehpour, Y.; Joo, S. W.; Min, B.; Oh, T. H. Structural studies and optical and electrical properties of novel Gd3+-doped Sb2Se3 nanorods. J. Nanomater. 2012, 2012, 983150.

25. Ruiz-Ortega, R. C.; Esquivel-Mendez, L. A.; Gonzalez-Trujillo, M. A.; Hernandez-Vasquez, C.; Matsumoto, Y.; Albor-Aguilera, M. L. Comprehensive analysis of CdS ultrathin films modified by the substrate position inside the reactor container using the CBD technique. ACS. Omega. 2023, 8, 31725-37.

26. Najm, A. S.; Naeem, H. S.; Majdi, H. S.; et al. An in-depth analysis of nucleation and growth mechanism of CdS thin film synthesized by chemical bath deposition (CBD) technique. Sci. Rep. 2022, 12, 15295.

27. Safi, A. A.; Ibrahim, I. M. The effect of rare-earth doping on CdS nanostructure: structural, optical and photoconductivity properties. Iraqi. J. Phys. 2019, 17, 108-18.

28. Kausar, R.; Khan, M. A.; Rasool, R. T.; Arshad, M.; Ashraf, G. A. Structural, morphological, spectral, XPS, and dielectric properties of Ba4Co2NdxFe36-xO60 nanocrystalline materials. Chem. Pap. 2024, 78, 5349-66.

29. Zhang, Y.; Ran, X.; Fu, H.; et al. Band alignment tunning via the facets of CdS nanocrystals with g-C3N4 for unveiling their enhanced photocatalytical property. Adv. Funct. Mater. 2024, 34, 2404585.

30. Yang, W.; Kim, J. H.; Hutter, O. S.; et al. Benchmark performance of low-cost Sb2Se3 photocathodes for unassisted solar overall water splitting. Nat. Commun. 2020, 11, 861.

31. Li, J.; Zhao, Y.; Li, C.; et al. Hydrazine hydrate-induced surface modification of CdS electron transport layer enables 10.30%-efficient Sb2(S,Se)3 planar solar cells. Adv. Sci. 2022, 9, 2202356.

32. Wang, X.; Guo, H.; Chen, Z.; et al. Enhancement of Sb2Se3 thin-film solar cell photoelectric properties by addition of interlayer CeO2. Solar. Energy. 2019, 188, 218-23.

33. Qi, L.; Cölfen, H.; Antonietti, M. Synthesis and characterization of CdS nanoparticles stabilized by double-hydrophilic block copolymers. Nano. Lett. 2000, 1, 61-5.

34. Gu, Y.; Liang, W.; Che, Y.; et al. Solvent annealing enabling reconstruction of cadmium sulfide film for improved heterojunction quality and photovoltaic performance of antimony selenosulfide solar cells. Adv. Funct. Mater. 2023, 34, 2311577.

35. Zhou, J.; Meng, D.; Yang, T.; et al. Enhanced charge carrier transport via efficient grain conduction mode for Sb2Se3 solar cell applications. Appl. Surf. Sci. 2022, 591, 153169.

36. Li, Z.; Chen, X.; Zhu, H.; et al. Sb2Se3 thin film solar cells in substrate configuration and the back contact selenization. Sol. Energy. Mater. Sol. Cells. 2017, 161, 190-6.

37. Liang, G.; Luo, Y.; Chen, S.; et al. Sputtered and selenized Sb2Se3 thin-film solar cells with open-circuit voltage exceeding 500 mV. Nano. Energy. 2020, 73, 104806.

38. Mohamed, N. A.; Kiong, T. S.; Ismail, A. F. Revolutionizing water splitting: the role of light rare earth elements (LREEs) in photoelectrochemical and electrochemical advances. Coord. Chem. Rev. 2025, 543, 216917.

39. Cai, Z.; Che, B.; Gu, Y.; et al. Active passivation of anion vacancies in antimony selenide film for efficient solar cells. Adv. Mater. 2024, 36, e2404826.

40. Janesko, B. G. Replacing hybrid density functional theory: motivation and recent advances. Chem. Soc. Rev. 2021, 50, 8470-95.

41. Shinde, R.; Yamijala, S. S. R. K. C.; Wong, B. M. Improved band gaps and structural properties from Wannier-Fermi-Löwdin self-interaction corrections for periodic systems. J. Phys. Condens. Matter. 2021, 33, 115501.

42. Mo, Y.; Li, C.; Yang, J.; et al. High-efficiency all-antimony chalcogenide tandem solar cells via thermal-evaporated CdS interface engineering. Adv. Mater. 2025, 37, e06372.

43. Chen, S.; Wang, X.; Chen, X.; et al. Self-regulated growth of large-grain Sb2Se3 thin films for high-efficiency solar cells. Adv. Funct. Mater. 2024, 34, 2402978.

44. Liu, Z.; Wang, L.; Yu, X.; et al. Piezoelectric-effect-enhanced full-spectrum photoelectrocatalysis in p-n heterojunction. Adv. Funct. Mater. 2019, 29, 1807279.

45. Li, Y.; Wang, K.; Huang, D.; et al. CdxZn1-xS/Sb2Se3 thin film photocathode for efficient solar water splitting. Appl. Catal. B. Environ. 2021, 286, 119872.

46. Yang, Y.; Zhang, T.; Zhu, H.; et al. Optimizing crystal orientation and defect mitigation in antimony selenide thin-film solar cells through buffer layer energy band adjustment. Small 2024, 20, e2403292.

47. Shen, K.; Zhang, Y.; Wang, X.; et al. Efficient and stable planar n-i-p Sb2Se3 solar cells enabled by oriented 1D trigonal selenium structures. Adv. Sci. 2020, 7, 2001013.

48. Zhang, T.; Yang, Y.; Dong, J.; et al. Regulation of the charge carrier dynamics in antimony selenide thin-film solar cells based on the effective diffusion of ions at the heterojunction interface. Adv. Funct. Mater. 2024, 35, 2417868.

49. Santakrus Singh, N.; Jain, A.; Kapoor, A. Determination of the solar cell junction ideality factor using special trans function theory (STFT). Sol. Energy. Mater. Sol. Cells. 2009, 93, 1423-6.

50. Chen, S.; Ye, Y. A.; Ishaq, M.; et al. Simultaneous band alignment modulation and carrier dynamics optimization enable highest efficiency in Cd-free Sb2Se3 solar cells. Adv. Funct. Mater. 2024, 34, 2403934.

51. Chen, G.; Zhao, J.; Chen, S.; et al. Perspective of environmentally friendly antimony selenide-based solar cell. Appl. Phys. Lett. 2024, 125, 200502.

52. Chen, S.; Fu, Y.; Ishaq, M.; et al. Carrier recombination suppression and transport enhancement enable high-performance self-powered broadband 3 photodetectors. InfoMat 2023, 5, e12400.

53. Yang, J.; Chen, M.; Chen, G.; et al. Back interface and absorber bulk deep-level trap optimization enables highly efficient flexible antimony triselenide solar cell. Adv. Sci. 2024, 11, e2310193.

54. Chen, X.; Zhao, Y.; Li, C.; et al. Interfacial engineering by self-assembled monolayer for high-performance Sb2S3 solar cells. Adv. Energy. Mater. 2024, 14, 2400441.

55. Li, K.; Yang, J.; Cai, Z.; et al. Effect of energy-driven molecular precursor decomposition on the crystal orientation of antimony selenide film and solar cell efficiency. Small. Method. 2024, 8, e2400227.

56. Wang, S.; Zhao, Y.; Che, B.; et al. A novel multi-sulfur source collaborative chemical bath deposition technology enables 8%-efficiency Sb2S3 planar solar cells. Adv. Mater. 2022, 34, e2206242.

57. Gong, Y.; Qiu, R.; Niu, C.; et al. Ag Incorporation with controlled grain growth enables 12.5% efficient kesterite solar cell with open circuit voltage reached 64.2% shockley-queisser limit. Adv. Funct. Mater. 2021, 31, 2101927.

Energy Materials
ISSN 2770-5900 (Online)
Follow Us

Portico

All published articles are preserved here permanently:

https://www.portico.org/publishers/oae/

Portico

All published articles are preserved here permanently:

https://www.portico.org/publishers/oae/