REFERENCES

1. Ahuis, M.; Doose, S.; Vogt, D.; Michalowski, P.; Zellmer, S.; Kwade, A. Recycling of solid-state batteries. Nat. Energy. 2024, 9, 373-85.

2. Yang, M.; Zhang, J.; Wang, X.; et al. Deep eutectic solvent additive induced inorganic SEI and an organic buffer layer synergistic protected Li anode for durable Li-CO₂ batteries. Adv. Energy. Mater. 2025, 15, 2405628.

3. Al-abbasi, M.; Zhao, Y.; He, H.; et al. Challenges and protective strategies on zinc anode toward practical aqueous zinc-ion batteries. Carbon. Neutral. 2024, 3, 108-41.

4. Liang, Y.; Yao, Y. Designing modern aqueous batteries. Nat. Rev. Mater. 2023, 8, 109-22.

5. Luo, C.; Lei, H.; Xiao, Y.; et al. Recent development in addressing challenges and implementing strategies for manganese dioxide cathodes in aqueous zinc ion batteries. Energy. Mater. 2024, 4, 400036.

6. Li, Y.; Guan, Q.; Cheng, J.; Wang, B. Amorphous H_0.82MoO_3.26 cathodes based long cyclelife fiber-shaped Zn-ion battery for wearable sensors. Energy. Storage. Mater. 2022, 49, 227-35.

7. Zhao, Y.; Chen, X.; Guo, W.; Zha, C. Emerging strategies for the improvement of modifications in aqueous rechargeable zinc-iodine batteries: cathode, anode, separator, and electrolyte. Carbon. Neutral. 2024, 3, 918-49.

8. Guo, W.; Dun, C.; Yu, C.; et al. Mismatching integration-enabled strains and defects engineering in LDH microstructure for high-rate and long-life charge storage. Nat. Commun. 2022, 13, 1409.

9. Lin, H.; Zeng, L.; Lin, C.; et al. Interfacial regulation via configuration screening of a disodium naphthalenedisulfonate additive enabled high-performance wide-pH Zn-based batteries. Energy. Environ. Sci. 2025, 18, 1282-93.

10. Huang, S.; Zhang, P.; Lu, J.; et al. Molecularly engineered multifunctional imide derivatives for practical Zn metal full cells. Energy. Environ. Sci. 2024, 17, 7870-81.

11. Chen, M.; Zhang, S.; Zou, Z.; et al. Review of vanadium-based oxide cathodes as aqueous zinc-ion batteries. Rare. Metals. 2023, 42, 2868-905.

12. Han, W.; Liu, G.; Seo, W.; Lee, H.; Chu, H.; Yang, W. Nitrogen-doped chain-like carbon nanospheres with tunable interlayer distance for superior pseudocapacitance-dominated zinc- and potassium-ion storage. Carbon 2021, 184, 534-43.

13. Miao, L.; Guo, Z.; Jiao, L. Insights into the design of mildly acidic aqueous electrolytes for improved stability of Zn anode performance in zinc-ion batteries. Energy. Mater. 2023, 3, 300014.

14. Wang, K.; Baule, N.; Jin, H.; et al. Multifunctional zinc silicate coating layer for high-performance aqueous zinc-ion batteries. Energy. Mater. 2025, 5, 500012.

15. Wang, R.; Liu, Z.; Wan, J.; et al. Eutectic network synergy interface modification strategy to realize high-performance Zn-I₂ batteries. Adv. Energy. Mater. 2024, 14, 2402900.

16. Ballas, E.; Nimkar, A.; Bergman, G.; et al. Self-discharge in flowless Zn-Br₂ batteries and its mitigation. Energy. Storage. Mater. 2024, 70, 103461.

17. Li, H.; Hao, J.; Qiao, S. Z. AI-driven electrolyte additive selection to boost aqueous Zn-ion batteries stability. Adv. Mater. 2024, 36, e2411991.

18. Wu, C.; Sun, C.; Ren, K.; et al. 2-methyl imidazole electrolyte additive enabling ultra-stable Zn anode. Chem. Eng. J. 2023, 452, 139465.

19. Xiong, P.; Lin, C.; Wei, Y.; et al. Charge-transfer complex-based artificial layers for stable and efficient Zn metal anodes. ACS. Energy. Lett. 2023, 8, 2718-27.

20. Song, B.; Lu, Q.; Wang, X.; Xiong, P. Promoted de-solvation effect and dendrite-free Zn deposition enabled by in-situ formed interphase layer for high-performance zinc-ion batteries. Energy. Mater. 2025, 5, 500031.

21. Xiong, L.; Fu, H.; Han, W.; et al. Robust ZnS interphase for stable Zn metal anode of high-performance aqueous secondary batteries. Int. J. Miner. Metall. Mater. 2022, 29, 1053-60.

22. Chen, A.; Zhao, C.; Guo, Z.; et al. Fast-growing multifunctional ZnMoO₄ protection layer enable dendrite-free and hydrogen-suppressed Zn anode. Energy. Storage. Mater. 2022, 44, 353-9.

23. Han, W.; Xiong, L.; Wang, M.; et al. Interface engineering via in-situ electrochemical induced ZnSe for a stabilized zinc metal anode. Chem. Eng. J. 2022, 442, 136247.

24. Ren, Q.; Tang, X.; He, K.; et al. Long-cycling zinc metal anodes enabled by an in situ constructed ZnO coating layer. Adv. Funct. Mater. 2024, 34, 2312220.

25. Wang, W.; Huang, G.; Wang, Y.; et al. Organic acid etching strategy for dendrite suppression in aqueous zinc-ion batteries. Adv. Energy. Mater. 2022, 12, 2102797.

26. Tao, F.; Liu, Y.; Ren, X.; et al. Different surface modification methods and coating materials of zinc metal anode. J. Energy. Chem. 2022, 66, 397-412.

27. Pan, H.; Shao, Y.; Yan, P.; et al. Reversible aqueous zinc/manganese oxide energy storage from conversion reactions. Nat. Energy. 2016, 1, 16039.

28. Chu, Y.; Zhang, S.; Wu, S.; Hu, Z.; Cui, G.; Luo, J. In situ built interphase with high interface energy and fast kinetics for high performance Zn metal anodes. Energy. Environ. Sci. 2021, 14, 3609-20.

29. Cao, L.; Li, D.; Pollard, T.; et al. Fluorinated interphase enables reversible aqueous zinc battery chemistries. Nat. Nanotechnol. 2021, 16, 902-10.

30. Zhang, S.; Hao, J.; Luo, D.; et al. Dual-function electrolyte additive for highly reversible Zn anode. Adv. Energy. Mater. 2021, 11, 2102010.

31. Cao, L.; Li, D.; Hu, E.; et al. Solvation structure design for aqueous Zn metal batteries. J. Am. Chem. Soc. 2020, 142, 21404-9.

32. Yan, M.; Xu, C.; Sun, Y.; Pan, H.; Li, H. Manipulating Zn anode reactions through salt anion involving hydrogen bonding network in aqueous electrolytes with PEO additive. Nano. Energy. 2021, 82, 105739.

33. Zhang, J.; Lin, C.; Zeng, L.; et al. A hydrogel electrolyte with high adaptability over a wide temperature range and mechanical stress for long-life flexible zinc-ion batteries. Small 2024, 20, e2312116.

34. Zhou, L.; Wu, C.; Yu, F.; et al. Dislocation effect boosting the electrochemical properties of prussian blue analogues for 2.6 V high-voltage aqueous zinc-based batteries. ACS. Appl. Mater. Interfaces. 2024, 16, 47454-63.

35. Zhang, F.; Meng, Q.; Qian, J. W.; et al. Selective interface engineering with large π-conjugated molecules enables durable Zn anodes. Angew. Chem. Int. Ed. 2025, 64, e202425487.

36. Li, R.; Li, M.; Chao, Y.; et al. Hexaoxacyclooctadecane induced interfacial engineering to achieve dendrite-free Zn ion batteries. Energy. Storage. Mater. 2022, 46, 605-12.

37. Zhang, Y.; Ao, H.; Dong, Q.; et al. Electrolytes additives for Zn metal anodes: regulation mechanism and current perspectives. Rare. Metals. 2024, 43, 4162-97.

38. Zhang, Q.; Luan, J.; Fu, L.; et al. The three-dimensional dendrite-free zinc anode on a copper mesh with a zinc-oriented polyacrylamide electrolyte additive. Angew. Chem. Int. Ed. 2019, 58, 15841-7.

39. Wang, D.; Lv, D.; Liu, H.; et al. In situ formation of nitrogen-rich solid electrolyte interphase and simultaneous regulating solvation structures for advanced Zn metal batteries. Angew. Chem. Int. Ed. 2022, 61, e202212839.

40. Huang, S.; Fu, H.; Kwon, H. M.; et al. Stereoisomerism of multi-functional electrolyte additives for initially anodeless aqueous zinc metal batteries. Nat. Commun. 2025, 16, 6117.

41. Guo, J.; Abbas, S. C.; Huang, H.; et al. Rational design of pyrrolic-N dominated carbon material derived from aminated lignin for Zn-ion supercapacitors. J. Colloid. Interface. Sci. 2023, 641, 155-65.

42. Cui, F.; Hu, F.; Yu, X.; Guan, C.; Song, G.; Zhu, K. In-situ tuning the NH₄⁺ extraction in (NH₄)₂V₄O₉ nanosheets towards high performance aqueous zinc ion batteries. J. Power. Sources. 2021, 492, 229629.

43. Han, W.; Lee, H.; Liu, Y.; et al. Toward highly reversible aqueous zinc-ion batteries: nanoscale-regulated zinc nucleation via graphene quantum dots functionalized with multiple functional groups. Chem. Eng. J. 2023, 452, 139090.

44. Hu, F.; Cui, Z.; Dong, Z.; et al. Zwitterionic gemini additive as interface engineers for long-life aqueous Zn/TEMPO flow batteries with enhanced areal capacity. Energy. Mater. 2025, 5, 500078.

45. Hieu, L. T.; So, S.; Kim, I. T.; Hur, J. Zn anode with flexible β-PVDF coating for aqueous Zn-ion batteries with long cycle life. Chem. Eng. J. 2021, 411, 128584.

46. Feng, H.; Zhou, W.; Chen, Z.; et al. Trace amounts of multifunctional electrolyte additives enhance cyclic stability of high-rate aqueous zinc-ion batteries. Small 2024, 20, e2407238.

47. Zhang, H.; Guo, R.; Li, S.; et al. Graphene quantum dots enable dendrite-free zinc ion battery. Nano. Energy. 2022, 92, 106752.

48. Chen, D.; Ma, X.; Xu, W.; et al. Disrupting hydrogen bond network connectivity with a double-site additive for long-life aqueous zinc metal batteries. Exploration 2025, 5, 20240007.

49. Zhang, F.; Li, S.; Xia, L.; et al. Bifunctional electrolyte addition for longer life and higher capacity of aqueous zinc-ion hybrid supercapacitors. Rare. Metals. 2024, 43, 5060-9.

50. Zhong, Y.; Cheng, Z.; Zhang, H.; et al. Monosodium glutamate, an effective electrolyte additive to enhance cycling performance of Zn anode in aqueous battery. Nano. Energy. 2022, 98, 107220.

51. Zhao, Z.; Huang, Y.; Guo, B.; et al. Malic acid additive with a dual regulating mechanism for high-performances aqueous zinc-ion batteries. Chem. Eng. J. 2024, 500, 157431.

52. Zheng, X.; Han, B.; Sun, J.; et al. Polyetheramine nematic spatial effects reshape the inner/outer helmholtz planes for energetic zinc batteries. Adv. Funct. Mater. 2025, 35, 2420434.

53. Wang, L.; Yu, H.; Chen, D.; et al. Steric hindrance and orientation polarization by a zwitterionic additive to stabilize zinc metal anodes. Carbon. Neutral. 2024, 3, 996-1008.

54. Song, Y.; Wang, X.; Liu, C.; et al. A widely used nonionic surfactant with desired functional groups as aqueous electrolyte additives for stabilizing Zn anode. Rare. Metals. 2024, 43, 3692-701.

55. Zhang, S. J.; Hao, J.; Wu, H.; Chen, Q.; Ye, C.; Qiao, S. Z. Protein interfacial gelation toward shuttle-free and dendrite-free Zn-iodine batteries. Adv. Mater. 2024, 36, e2404011.

56. Wu, K.; Wang, Y.; Wan, Y.; et al. Nitrogen and oxygen Co-doped graphene quantum dots as a trace amphipathic additive for dendrite-free Zn anodes. Adv. Funct. Mater. 2025, 35, 2412027.

57. Yang, Z.; Lai, F.; Mao, Q.; et al. Reversing zincophobic/hydrophilic nature of metal-N-C via metal-coordination interaction for dendrite-free Zn anode with high depth-of-discharge. Adv. Mater. 2024, 36, e2311637.

58. Deng, S.; Sun, Y.; Yang, Z.; et al. Zwitterion-separated ion pair dominated additive-electrolyte structure for ultra-stable aqueous zinc ion batteries. Adv. Funct. Materials. 2024, 34, 2408546.

59. Huang, C.; Liu, S.; Feng, J.; et al. Optimizing engineering of rechargeable aqueous zinc ion batteries to enhance the zinc ions storage properties of cathode material. J. Power. Sources. 2021, 490, 229528.

60. Li, Y.; Liu, L.; Zhang, H.; et al. Bi-functional green additive anchoring interface enables stable zinc metal anodes for aqueous zinc-ions batteries. Adv. Funct. Mater. 2025, 35, 2410855.

61. Han, W.; Chen, D.; Li, Q.; Liu, W.; Chu, H.; Rui, X. Ultrafast flame growth of carbon nanotubes for high-rate sodium storage. J. Power. Sources. 2019, 439, 227072.