fig19
Figure 19. (A) Diagram of HOMO and LUMO energy levels showing electron acceptance and donation ability of EC, PC, and DEGDME. (b) AIMD simulation snapshots of DEGDME-based electrolyte. (c) Radial distribution functions g(r) of Na-O and Na-F pairs in both electrolytes. (d) Solvation energy and (e) desolvation energy of Na+-solvent complexes. (f) Schematic illustration of reaction kinetics of Sn@NC full cells with DEGDME-based electrolyte. (B) (a) Cyclic performances at 1.0 A g-1 in both electrolytes (b) Long-term cycling for 10,000 cycles of composite anodes at 5.0 A g-1 in DEGDME-based electrolyte. Reproduced with permission from[75]. Copyright © 2023 John Wiley & Sons, Inc.