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Figure 1. (A) The mechanism of C–H bond cleavage of methane at low-temperature reaction systems[54]. Copyright 2019, Elsevier; (B) Computational studies of reaction pathway. Minimum-energy paths and reaction schematic for formation of acetic acid from CH4, CO, and O2 on Rh1O5/ZSM-5. Intermediates and transition states for a complete catalytic cycle, starting with Rh1O5 (c1). Transition states are highlighted with the double dagger symbols[47]. Copyright 2018, Springer Nature; (C) Comparison of the performance and CH3OH selectivity of different catalysts for methane conversion in the methane selective oxidation process[28]. Copyright 2024, Springer Nature.






