fig6

Rational design of single-atom catalysts for efficient hydrogenation of nitro compounds

Figure 6. (A) A graphic illustration for designing nanocarbon edge anchored high-density Pt1 atoms for catalytic nitro compounds[123]; (B) Side views of real space electron redistribution between graphene and GDY[87]; (C) Schematic illustration of the proposed mechanism of 4-NP reduction catalyzed by Pd1/GDY/G[87]; (D) Schematic illustration for the construction of Pd1/In2O3-x[139]; (E) Schematic illustration of H2 dissociation and H diffusion on Pt1/Ni(111)[148]; (F) Time courses of the conversion for Ni nanocrystals, Pt1/Ni nanocrystals, Pt clusters/Ni nanocrystals, and Pt/C in selective hydrogenation of 3-nitrostyrene under 3 atm of H2 at 40 °C[148]. Pt1: Single Pt atoms; GDY/G: graphite diacetylene/graphene; NP: nanoparticle.

Chemical Synthesis
ISSN 2769-5247 (Online)

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