fig18

MOFs-based single/dual-atom catalysts: atomically active sites engineering for efficient CO<sub>2</sub> reduction

Figure 18. (A) FT-EXAFS fitting and structural model of CA/Ni1CuNP N-C; (B) Photocatalytic CO2RR product efficiency of CH4, CO, and C2H6 with different percentage of Ni1CuNP N-C; (C) Diagram of photocatalytic CO2RR mechanism over Ni1CuNP N-C; (A-C) are quoted with permission from Pan et al.[278]; (D) AC-HADDF-STEM image of CoNX/TiO2; (E and F) CO/CH4 yields (E) and the corresponding TCEN (F) of CoNX/TiO2 and other reference samples; (D-F) are quoted with permission from Zeng et al.[279]; (G) Normalized XANES spectra of the Cu K-edge for Cu SAs/UiO-66-NH2 and other samples; (H and I) CH3OH/CH3CH2OH yields (H) and comparative rates of formation (I) by Cu SAs/UiO-66-NH2; (G-I) are quoted with permission from Wang et al.[280]. FT: Fourier transform; EXAFS: extended X-ray absorption fine structure; CO2RR: CO2 reduction reaction; XANES: X-ray absorption near-edge structure; TCEN: total carbon-based product.

Chemical Synthesis
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