REFERENCES

1. Hu, F.; Hu, Z.; Liu, Y.; et al. Aqueous sol-gel synthesis and shaping of covalent organic frameworks. J. Am. Chem. Soc. 2023, 145, 27718-27.

2. Tian, Y.; Chen, Y.; Wang, S.; et al. Ultrathin aerogel-structured micro/nanofiber metafabric via dual air-gelation synthesis for self-sustainable heating. Nat. Commun. 2024, 15, 6416.

3. Hermans, T. M.; Singh, N. Chemically fueled autonomous Sol → Gel → Sol → Gel → Sol transitions. Angew. Chem. 2023, 135, e202301529.

4. Lim, H. W.; Lee, T. K.; Park, S.; et al. A ruthenium-titania core-shell nanocluster catalyst for efficient and durable alkaline hydrogen evolution. Energy. Environ. Sci. 2025, 18, 2243-53.

5. Xie, W.; Huang, X. Y.; Zhu, C.; et al. Synthesis of ordered mesoporous metal oxides by solvent evaporation-induced cooperative assembly. Nat. Protoc. 2026, 21, 987-1020.

6. Li, J.; Liu, S.; Xie, Y.; et al. Nanoemulsion-assisted assembly and polymerization towards core-shell magnetic mesoporous melamine-formaldehyde resin microspheres. Chin. Chem. Lett. 2026, 37, 111433.

7. Xie, Y.; Xie, W.; Li, J.; Deng, Y.; Cheng, X. Ternary interactions balance enabled sequential assembly toward the synthesis of hierarchically mesoporous metal hydroxide nanoparticles. J. Am. Chem. Soc. 2025, 147, 28882-92.

8. Tong, T.; Hu, H.; Xie, Y.; Jin, J. Advancements in liquid marbles as an open microfluidic platform: Rapid formation, robust manipulation, and revolutionary applications. Droplet 2025, 4, e160.

9. Xing, E.; Yu, Y.; Yu, H.; et al. Solvation-layer mediated interfacial assembly for surface topological engineering of mesoporous microcarriers. ACS. Nano. 2025, 19, 33798-812.

10. Millot, Y.; Hervier, A.; Ayari, J.; Hmili, N.; Blanchard, J.; Boujday, S. Revisiting alkoxysilane assembly on silica surfaces: grafting versus homo-condensation in solution. J. Am. Chem. Soc. 2023, 145, 6671-81.

11. Wolf, A.; Sauer, J.; Hurle, K.; Müssig, S.; Mandel, K. Magnetic supraparticles capable of recording high‐temperature events. Adv. Funct. Mater. 2024, 34, 2316212.

12. Chen, J.; Hua, Z.; Yan, Y.; Zakhidov, A. A.; Baughman, R. H.; Xu, L. Template synthesis of ordered arrays of mesoporous titania spheres. Chem. Commun. (Camb). 2010, 46, 1872-4.

13. Xie, W.; Huang, X.; Zhu, C.; et al. A versatile synthesis platform based on polymer cubosomes for a library of highly ordered nanoporous metal oxides particles. Adv. Mater. 2024, 36, e2313920.

14. Kuang, J.; Wang, Q.; Jia, Z.; et al. Ablation-resistant yttrium-modified high-entropy refractory metal silicide (NbMoTaW)Si2 coating for oxidizing environments up to 2,100 °C. Mater. Today. 2024, 80, 156-66.

15. Ren, Z.; Wang, M.; Chen, S.; et al. Suppressing the formation of OP4 phase in P2-Structured Na0.67Ni0.1Co0.1Mn0.8O2 by in-situ formed NiF2 layer. Energy. Storage. Mater. 2023, 60, 102815.

16. Pan, P.; Liu, Q.; Hu, L.; et al. Dual-template induced interfacial assembly of yolk-shell magnetic mesoporous polydopamine vesicles with tunable cavity for enhanced photothermal antibacterial. Chem. Eng. J. 2023, 472, 144972.

17. Xie, W.; Ren, Y.; Jiang, F.; et al. Solvent-pair surfactants enabled assembly of clusters and copolymers towards programmed mesoporous metal oxides. Nat. Commun. 2023, 14, 8493.

18. Quan, Q.; Fan, C.; Pan, N.; et al. Tough and stretchable phenolic-reinforced double network deep eutectic solvent gels for multifunctional sensors with environmental adaptability. Adv. Funct. Mater. 2023, 33, 2303381.

19. Li, K.; Ni, X.; Li, D.; et al. Efficient construction of low shrinkage xerogels via coordination-catalyzed in-situ polymerization for activated carbon xerogels with multi-dyes adsorption. Nano. Materials. Science. 2025, 7, 674-85.

20. Al‐Muhtaseb, S.; Ritter, J. Preparation and properties of resorcinol-formaldehyde organic and carbon gels. Adv. Mater. 2003, 15, 101-14.

21. Zhou, X.; Ma, J.; Ren, Y.; Zou, Y.; Zhao, D.; Deng, Y. Bridging molecule assisted organic-inorganic interface coassembly to rationally construct metal oxide mesostructures. Chem. Mater. 2022, 34, 6824-34.

22. Feng, B.; Wu, Y.; Ren, Y.; et al. Self-template synthesis of mesoporous Au-SnO2 nanospheres for low-temperature detection of triethylamine vapor. Sensor. Actuat. B-Chem. 2022, 356, 131358.

23. Ren, Y.; Xie, W.; Li, Y.; et al. Noble metal nanoparticles decorated metal oxide semiconducting nanowire arrays interwoven into 3D mesoporous superstructures for low-temperature gas sensing. ACS. Cent. Sci. 2021, 7, 1885-97.

24. Luo, Y.; Wang, X.; Wang, P.; Chen, F.; Yu, H. Inorganic/organic hybrid interfacial internal electric field modulated charge separation of resorcinol-formaldehyde resin for boosting photocatalytic H2O2 production. Chem. Eng. J. 2024, 497, 154886.

25. Shiraishi, Y.; Matsumoto, M.; Ichikawa, S.; Tanaka, S.; Hirai, T. Polythiophene-doped resorcinol-formaldehyde resin photocatalysts for solar-to-hydrogen peroxide energy conversion. J. Am. Chem. Soc. 2021, 143, 12590-9.

26. Itoh, Y.; Fu, T.; Champagne, P. L.; et al. Electric double-layer synthesis of a spongelike, lightweight reticular membrane. Science 2025, 389, 73-7.

27. Yu, X. Q.; Wu, J.; Wang, J. W.; et al. Facile access to high solid content monodispersed microspheres via dual-component surfactants regulation toward high-performance colloidal photonic crystals. Adv. Mater. 2024, 36, e2312879.

28. Parker, C. J.; Krishnamurthi, V.; Zuraiqi, K.; et al. Synthesis of planet-like liquid metal nanodroplets with promising properties for catalysis. Adv. Funct. Mater. 2023, 34, 2304248.

29. Jung, W.; Vong, M. H.; Kwon, K.; et al. Giant decrease in interfacial energy of liquid metals by native oxides. Adv. Mater. 2024, 36, e2406783.

30. Chen, Y.; Liu, L.; Li, J.; et al. Flexible gas sensors based on in situ fabricated hierarchically porous SnO2/PEDOT:PSS sensing layer. Chin. Chem. Lett. 2026, 37, 111654.

31. Wang, F.; Zhong, H.; Chen, Z.; et al. Porous 2D CuO nanosheets for efficient triethylamine detection at low temperature. Chin. Chem. Lett. 2023, 34, 107392.

32. Wang, X.; Zhou, J.; Xing, W.; et al. Resorcinol-formaldehyde resin-based porous carbon spheres with high CO2 capture capacities. J. Energy. Chem. 2017, 26, 1007-13.

33. Zhang, Z.; Liu, M.; Ibrahim, M. M.; et al. Flexible polystyrene/graphene composites with epsilon-near-zero properties. Adv. Compos. Hybrid. Mater. 2022, 5, 1054-66.

34. Li, H. J.; Chen, Y.; Wang, H.; et al. Amide (n, π*) Transitions enabled clusteroluminescence in solid-state carbon dots. Adv. Funct. Mater. 2023, 33, 2302862.

35. Xiao, P.; Zhang, Z.; Ge, J.; et al. Surface passivation of intensely luminescent all-inorganic nanocrystals and their direct optical patterning. Nat. Commun. 2023, 14, 49.

36. Lan, Y.; Zheng, G. S.; Song, R. W.; et al. Low-temperature molten-salt enabled synthesis of highly-efficient solid-state emitting carbon dots optimized using machine learning. Nat. Commun. 2025, 16, 8167.

37. Deng, S.; Locklin, J.; Patton, D.; Baba, A.; Advincula, R. C. Thiophene dendron jacketed poly(amidoamine) dendrimers: nanoparticle synthesis and adsorption on graphite. J. Am. Chem. Soc. 2005, 127, 1744-51.

38. Guo, Z. M.; Gao, Y. X.; Lin, T. Synthesis of nanosized tungsten carbide from phenol formaldehyde resin coated precursors. Rare. Metals. 2008, 27, 201-4.

39. Wang, X.; Liao, Y.; Zhang, D.; Wen, T.; Zhong, Z. A review of Fe3O4 thin films: synthesis, modification and applications. J. Mater. Sci. Technol. 2018, 34, 1259-72.

40. Xu, Q.; Qu, H.; Wu, Z.; et al. Relaxation-enhanced polymer nanocomposites induced by bound polymer loops on the particle surfaces. Nat. Commun. 2025, 16, 9870.

41. Paris, J. L.; Gaspar, R.; Coelho, F.; De Beule, P. A. A.; Silva, B. F. B. Stability criterion for the assembly of core-shell lipid-polymer-nucleic acid nanoparticles. ACS. Nano. 2023, 17, 17587-94.

42. Lee, D.; Wolska-Pietkiewicz, M.; Badoni, S.; Grala, A.; Lewiński, J.; De Paëpe, G. Disclosing interfaces of ZnO nanocrystals using dynamic nuclear polarization: sol-gel versus organometallic approach. Angew. Chem. Int. Ed. Engl. 2019, 58, 17163-8.

43. Fijneman, A. J.; Högblom, J.; Palmlöf, M.; De With, G.; Persson, M.; Friedrich, H. Multiscale colloidal assembly of silica nanoparticles into microspheres with tunable mesopores. Adv. Funct. Mater. 2020, 30, 2002725.

44. Siegwardt, L.; Gallei, M. Complex 3D‐Printed Mechanochromic Materials with iridescent structural colors based on core-shell particles. Adv. Funct. Mater. 2023, 33, 2213099.

45. Lin, C.; Li, Y.; Yu, M.; Yang, P.; Lin, J. A facile synthesis and characterization of monodisperse spherical pigment particles with a core/shell structure. Adv. Funct. Mater. 2007, 17, 1459-65.

46. Chen, Z.; Chu, C.; Yao, D.; Li, Q.; Mao, S. Resorcinol-phthalaldehyde resins for photosynthesis of hydrogen peroxide: modulation of electronic structure and integration of dual channel pathway. Adv. Funct. Mater. 2024, 34, 2400506.

47. Li, J.; Liu, S.; Xie, Y.; et al. Core-shell magnetic mesoporous 3-aminophenol-formaldehyde resin microspheres with rich functional groups via interface co-assembly and polymerization. J. Mater. Chem. A. 2024, 12, 22627-36.

48. Zou, Y.; Sun, Z.; Wang, Q.; et al. Core-shell magnetic particles: tailored synthesis and applications. Chem. Rev. 2025, 125, 972-1048.

49. Sui, C.; Hsu, P. Standardizing the thermodynamic definition of daytime subambient radiative cooling. ACS. Energy. Lett. 2024, 9, 2997-3000.

50. Xu, H.; Wang, N.; Meng, R.; et al. Rapid grain growth to attain over 13% certified flexible CZTSSe solar cell. ACS. Energy. Lett. 2025, 10, 4644-54.

51. Qu, X.; Chu, F.; He, Y.; et al. Atomic-scale structural dynamics at a‐Si:H/c‐Si heterointerface during low-temperature thermal annealing. Adv. Funct. Mater. 2024, 35, 2413141.

52. Moreira, M.; Pires, A. L.; Ferreira‐Teixeira, S.; et al. Promoting surface conduction through scalable structure engineering of flexible topological insulator thin films. Adv. Funct. Mater. 2024, 34, 2405057.

53. Zhao, Q.; Tang, R.; Che, B.; et al. Grain-boundary elimination via liquid medium annealing toward high-efficiency Sb2Se3 solar cells. Adv. Mater. 2025, 37, e2414082.

54. Chai, Z.; Peng, B.; Ren, X.; Hong, K.; Chen, X. The microstructural evolution and relaxation strengthening for nano-grained Ni upon low-temperature annealing. Nano. Mater. Sci. 2024, 6, 726-34.

55. Gholami, F.; Yue, L.; Li, M.; et al. Fast and Efficient fabrication of functional electronic devices through grayscale digital light processing 3D printing. Adv. Mater. 2024, 36, e2408774.

56. Qian, Z.; Zhao, S.; Li, B.; Wu, G. P. Dual sacrificial strategy toward tough and recyclable CO2-sourced epoxy thermosets. Angew. Chem. Int. Ed. Engl. 2025, 64, e19660.

57. Yue, L.; Su, Y. L.; Li, M.; et al. Chemical circularity in 3D printing with biobased Δ-valerolactone. Adv. Mater. 2024, 36, e2310040.

58. Lee, Y. B.; Kim, Y. S.; Chen, C.; et al. Multimaterial 3D printing in activating bath enables in situ polymerization of thermosets with intricate geometries and diverse elastic behaviors. Adv. Mater. 2025, 37, e08568.

59. Li, Q.; Cai, S.; Feng, Z.; et al. Chemically recyclable carbon fiber reinforced polymer composites with ultrafast degradation rate via an epoxy monomer bearing four acetal groups. Adv. Funct. Mater. 2025, 36, e24492.

60. Yu, L.; Pan, P.; Yu, B.; et al. Interface assembly to magnetic mesoporous organosilica microspheres with tunable surface roughness as advanced catalyst carriers and adsorbents. ACS. Appl. Mater. Interfaces. 2021, 13, 36138-46.