REFERENCES
2. Tian, Y.; Zeng, G.; Rutt, A.; et al. Promises and challenges of next-generation “beyond Li-ion” batteries for electric vehicles and grid decarbonization. Chem. Rev. 2021, 121, 1623-69.
3. Bi, C. X.; Zhao, M.; Hou, L. P.; et al. Anode material options toward 500 Wh kg-1 lithium-sulfur batteries. Adv. Sci. 2022, 9, e2103910.
4. Chen, S.; Niu, C.; Lee, H.; et al. Critical parameters for evaluating coin cells and pouch cells of rechargeable Li-metal batteries. Joule 2019, 3, 1094-105.
5. Zhang, X.; Yang, Y.; Zhou, Z. Towards practical lithium-metal anodes. Chem. Soc. Rev. 2020, 49, 3040-71.
6. Kim, K.; Kang, J.; Lee, H. Hybrid thermoelectrochemical and concentration cells for harvesting low-grade waste heat. Chem. Eng. J. 2021, 426, 131797.
7. Lin, D.; Liu, Y.; Liang, Z.; et al. Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes. Nat. Nanotechnol. 2016, 11, 626-32.
8. Wu, C.; Huang, H.; Lu, W.; et al. Mg doped Li-LiB alloy with in situ formed lithiophilic LiB skeleton for lithium metal batteries. Adv. Sci. 2020, 7, 1902643.
9. Li, W.; Guo, X.; Song, K.; et al. Binder-induced ultrathin SEI for defect-passivated hard carbon enables highly reversible sodium-ion storage. Adv. Energy. Mater. 2023, 13, 2300648.
10. Yan, C.; Cheng, X. B.; Yao, Y. X.; et al. An armored mixed conductor interphase on a dendrite-free lithium-metal anode. Adv. Mater. 2018, 30, e1804461.
11. Zeng, Z.; Murugesan, V.; Han, K. S.; et al. Non-flammable electrolytes with high salt-to-solvent ratios for Li-ion and Li-metal batteries. Nat. Energy. 2018, 3, 674-81.
12. Wang, Y.; Dong, S.; Gao, Y.; et al. Difluoroester solvent toward fast-rate anion-intercalation lithium metal batteries under extreme conditions. Nat. Commun. 2024, 15, 5408.
13. Hao, Z.; Wang, C.; Wu, Y.; et al. Electronegative nanochannels accelerating lithium-ion transport for enabling highly stable and high‐rate lithium metal anodes. Adv. Energy. Mater. 2023, 13, 2204007.
14. Ji, Y.; Yuan, B.; Zhang, J.; et al. A single-layer piezoelectric composite separator for durable operation of Li metal anode at high rates. Energy. Environ. Mater. 2024, 7, e12510.
15. Sheng, L.; Xie, X.; Arbizzani, C.; et al. A tailored ceramic composite separator with electron-rich groups for high-performance lithium metal anode. J. Membr. Sci. 2022, 657, 120644.
16. Guo, X.; Xie, Z.; Wang, R.; et al. Interface-compatible gel-polymer electrolyte enabled by NaF-solubility-regulation toward all-climate solid-state sodium batteries. Angew. Chem. Int. Ed. Engl. 2024, 63, e202402245.
17. Xu, H.; Cao, G.; Shen, Y.; et al. Enabling argyrodite sulfides as superb solid-state electrolyte with remarkable interfacial stability against electrodes. Energy. Environ. Mater. 2022, 5, 852-64.
18. Zhu, L.; Chen, J.; Wang, Y.; et al. Tunneling interpenetrative lithium ion conduction channels in polymer-in-ceramic composite solid electrolytes. J. Am. Chem. Soc. 2024, 146, 6591-603.
19. Feng, X.; Wang, M.; Zheng, J.; Ge, J.; Yang, M.; Chen, W. Facile preparation of higher conductivity porous polyimide-based separators by phase inversion and its overcharge-sensitive modification for lithium-ion batteries. Batteries. Supercaps. 2023, 6, e202300244.
20. Huang, X.; He, R.; Li, M.; Chee, M. O. L.; Dong, P.; Lu, J. Functionalized separator for next-generation batteries. Mater. Today. 2020, 41, 143-55.
21. Hao, Z.; Wu, Y.; Zhao, Q.; et al. Functional separators regulating ion transport enabled by metal-organic frameworks for dendrite-free lithium metal anodes. Adv. Funct. Mater. 2021, 31, 2102938.
23. Li, J.; Chen, L.; Wang, F.; et al. Anionic metal-organic framework modified separator boosting efficient Li-ion transport. Chem. Eng. J. 2023, 451, 138536.
24. Zhang, T.; Chen, J.; Tian, T.; et al. Sustainable separators for high-performance lithium ion batteries enabled by chemical modifications. Adv. Funct. Mater. 2019, 29, 1902023.
25. Li, X.; Zhang, J.; Guo, X.; et al. An ultrathin nonporous polymer separator regulates Na transfer toward dendrite-free sodium storage batteries. Adv. Mater. 2023, 35, e2203547.
26. Guo, X.; Li, X.; Xu, Y.; Chen, J. Understanding the accelerated sodium-ion-transport mechanism of an interfacial modified polyacrylonitrile separator. J. Phys. Chem. C. 2022, 126, 8238-47.
27. Li, C.; Liu, S.; Shi, C.; et al. Two-dimensional molecular brush-functionalized porous bilayer composite separators toward ultrastable high-current density lithium metal anodes. Nat. Commun. 2019, 10, 1363.
28. Jung, A.; Lee, M. J.; Lee, S. W.; Cho, J.; Son, J. G.; Yeom, B. Phase separation-controlled assembly of hierarchically porous aramid nanofiber films for high-speed lithium-metal batteries. Small 2022, 18, e2205355.
29. Hu, W.; Fu, W.; Jhulki, S.; et al. Heat-resistant Al2O3 nanowire-polyetherimide separator for safer and faster lithium-ion batteries. J. Mater. Sci. Technol. 2023, 142, 112-20.
30. Ye, F.; Zhang, X.; Liao, K.; et al. A smart lithiophilic polymer filler in gel polymer electrolyte enables stable and dendrite-free Li metal anode. J. Mater. Chem. A. 2020, 8, 9733-42.
31. Wang, J.; Xu, Z.; Zhang, Q.; et al. Stable sodium-metal batteries in carbonate electrolytes achieved by bifunctional, sustainable separators with tailored alignment. Adv. Mater. 2022, 34, e2206367.
32. Hussain, A.; Mehmood, A.; Saleem, A.; et al. Polyetherimide membrane with tunable porous morphology for safe lithium metal-based batteries. Chem. Eng. J. 2023, 453, 139804.
33. Machatschek, R.; Heuchel, M.; Lendlein, A. Thin-layer studies on surface functionalization of polyetherimide: hydrolysis versus amidation. J. Mater. Res. 2022, 37, 67-76.
34. He, X.; Zhou, A.; Shi, C.; Zhang, J.; Li, W. Solvent resistant nanofiltration membranes using EDA-XDA co-crosslinked poly(ether imide). Sep. Purif. Technol. 2018, 206, 247-55.
35. Zhang, Y.; Yuan, J.; Song, Y.; et al. Tannic acid/polyethyleneimine-decorated polypropylene separators for Li-ion batteries and the role of the interfaces between separator and electrolyte. Electrochim. Acta. 2018, 275, 25-31.
36. Doyle, R. P.; Chen, X.; Macrae, M.; et al. Poly(ethylenimine)-based polymer blends as single-ion lithium conductors. Macromolecules 2014, 47, 3401-8.
37. Lee, J.; Park, H.; Hwang, J.; Noh, J.; Yu, C. Delocalized lithium ion flux by solid-state electrolyte composites coupled with 3D porous nanostructures for highly stable lithium metal batteries. ACS. Nano. 2023, 17, 16020-35.
38. Guo, Y.; Wu, Q.; Liu, L.; et al. Thermally conductive AlN-network shield for separators to achieve dendrite-free plating and fast Li-ion transport toward durable and high-rate lithium-metal anodes. Adv. Sci. 2022, 9, e2200411.
39. Jiao, S.; Ren, X.; Cao, R.; et al. Stable cycling of high-voltage lithium metal batteries in ether electrolytes. Nat. Energy. 2018, 3, 739-46.
40. Shi, J.; Fang, L.; Li, H.; Zhang, H.; Zhu, B.; Zhu, L. Improved thermal and electrochemical performances of PMMA modified PE separator skeleton prepared via dopamine-initiated ATRP for lithium ion batteries. J. Membr. Sci. 2013, 437, 160-8.
41. Zhang, H.; Sheng, L.; Bai, Y.; et al. Amino-functionalized Al2O3 particles coating separator with excellent lithium-ion transport properties for high-power density lithium-ion batteries. Adv. Eng. Mater. 2020, 22, 1901545.
42. Cai, Q.; Wang, J.; Jiao, Y.; et al. All-graphitic multilaminate mesoporous membranes by interlayer-confined molecular assembly. Small 2021, 17, e2101173.
43. Wang, C.; Zhao, X.; Li, D.; Yan, C.; Zhang, Q.; Fan, L. Z. Anion-modulated ion conductor with chain conformational transformation for stabilizing interfacial phase of high-voltage lithium metal batteries. Angew. Chem. Int. Ed. Engl. 2024, 63, e202317856.
44. Ha, H.; Kil, E.; Kwon, Y. H.; Kim, J. Y.; Lee, C. K.; Lee, S. UV-curable semi-interpenetrating polymer network-integrated, highly bendable plastic crystal composite electrolytes for shape-conformable all-solid-state lithium ion batteries. Energy. Environ. Sci. 2012, 5, 6491.
45. Yang, Y.; Yao, S.; Wu, Y.; et al. Hydrogen-bonded organic framework as superior separator with high lithium affinity C═N bond for low N/P ratio lithium metal batteries. Nano. Lett. 2023, 23, 5061-9.
46. Liu, P.; Yang, L.; Xiao, B.; et al. Revealing lithium battery gas generation for safer practical applications. Adv. Funct. Mater. 2022, 32, 2208586.
47. Jin, Y.; Zheng, Z.; Wei, D.; et al. Detection of micro-scale Li dendrite via H2 gas capture for early safety warning. Joule 2020, 4, 1714-29.
48. Lu, Z.; Yang, H.; Guo, Y.; et al. Electrolyte sieving chemistry in suppressing gas evolution of sodium-metal batteries. Angew. Chem. 2022, 134, e202206340.
49. Chazalviel, J. Electrochemical aspects of the generation of ramified metallic electrodeposits. Phys. Rev. A. 1990, 42, 7355-67.
50. Ren, W.; Zhu, K.; Zhang, W.; et al. Dendrite-free lithium metal battery enabled by dendritic mesoporous silica coated separator. Adv. Funct. Materials. 2023, 33, 2301586.
51. Chen, Y.; Mickel, P.; Pei, H.; et al. Bioinspired separator with ion-selective nanochannels for lithium metal batteries. ACS. Appl. Mater. Interfaces. 2023, 15, 18333-42.
52. Liao, C.; Mu, X.; Han, L.; et al. A flame-retardant, high ionic-conductivity and eco-friendly separator prepared by papermaking method for high-performance and superior safety lithium-ion batteries. Energy. Stor. Mater. 2022, 48, 123-32.
53. Zuo, L.; Ma, Q.; Xiao, P.; et al. Upgrading the separators integrated with desolvation and selective deposition toward the stable lithium metal batteries. Adv. Mater. 2024, 36, e2311529.
54. Yuan, B.; Feng, Y.; Qiu, X.; et al. A safe separator with heat-dispersing channels for high-rate lithium-ion batteries. Adv. Funct. Mater. 2024, 34, 2308929.
55. Ma, L.; Chen, R.; Hu, Y.; et al. Nanoporous and lyophilic battery separator from regenerated eggshell membrane with effective suppression of dendritic lithium growth. Energy. Storage. Mater. 2018, 14, 258-66.





